Let $X$ be, for simplicity, a finite set (with the discrete topology). Denote with $M(X)$ the set of probability measures on $X$ endowed with the weak topology. For $\mu\in M(X)$ and a (necessarily measurable) function $f:X\rightarrow[-1,1]$ denote with $E_{\mu}(f)$ the expected value of $f$.
For a (closed) set $A\subseteq M(X)$, define the lower expectation of $A$, denoted by $E(A)$, as the following functional of type $(X\rightarrow [-1,1])\rightarrow [-1,1]$:
$$E(A)(f)= \displaystyle \inf \{ E_{\mu}(f) \ | \ \mu \in A \}.$$
For a (closed) set $A\subseteq M(X)$ denote with $H(A)$ its convex hull of $A$, defined as expected.
It is easy to see that:
Proposition: For all $A,B\subseteq M(X)$, if $H(A)=H(B)$ then $E(A)=E(B)$.
Now my question is about the inverse direction of the previous statement.
QUESTION 1: Is it true that for $A,B\subseteq M(X)$, if $E(A)=E(B)$ then $H(A)=H(B)$?
QUESTION 2: What about restricting attention to functions $f$ of type $X\rightarrow [0,1]$?
Remark: note that, restricting even further to characteristic functions $f:X\rightarrow\{0,1\}$, the statement of QUESTION $1$ is not true anymore and the following is an example:
Example. Consider $X=\{a,b,c\}$, $\mu_{1}= \{ a\mapsto 0.3, b\mapsto 0.3, c\mapsto 0.4\}$, $\mu_{2}=\{ a\mapsto 0.4, b\mapsto 0.3, c\mapsto 0.3\}$ and $\mu_{3}=\{a\mapsto 0.5, b\mapsto 0.4, c\mapsto 0.1 \}$. Now consider $A=\{\mu_{1},\mu_{2}\}$ and $B=\{\mu_{1},\mu_{2},\mu_{3}\}$. Now $H(A)\neq H(B)$ because $\mu_{3}$ is not a convex combination of $\mu_{1}$ and $\mu_{2}$. Yet, for every set $Y\subseteq X$ (i.e., function $f:X\rightarrow\{0,1\}$, it holds that $E(A)(Y)=E(B)(Y)$.
There is a one-to-one correspondence between convex sets of probability distributions and affinely superadditive lower expectations (or lower previsions in Walley's terminology). You should check http://sites.poli.usp.br/p/fabio.cozman/research/credalsetstutorial/introduction/node5.html