for any vector $\xi \in \mathcal{H}$, there exist two vectors $x_i, x_k$ in the set $S$ such that $\langle x_i, \xi \rangle = \langle x_k, \xi \rangle$. (two such vectors may depend on $\xi$)
If the set S satisfies the above property, are there two identical vectors in it?
I have been trying to construct a counterexample, but I didn't make it.
Moreover, is this question easy to solve when the Hilbert space is separable?
We may replace the finite set with the set of pairwise differences of the vectors, and turn the problem into the following:
If $\mathcal H$ is infinite dimensional, then this is trivial, as we only need to pick any nonzero vector $\xi\in S^{\perp}$. Now we focus on the finite dimensional case.
We show that $S$ must contain the zero vector. If not, we may normalize $S$, i.e. assume $\|x_i\|=1$ for any $x_i\in S$. Let $\xi_1=x_1$, and we shall inductively construct $\xi_i$, such that $\xi$ has non-vanishing inner product with any of $x_1, x_2, \cdots, x_i$.
Assume we have constructed $\xi_1, \cdots, \xi_k$, if $(\xi_k, x_{k+1})\not=0$, then $\xi_{k+1}=\xi_k$ is fine. Otherwise, let $$\delta=\min_{i=1, 2, \cdots, k} |(\xi_k, x_i)|>0$$
Now $\xi_{k+1} = \xi_k + \frac{\delta}{2}x_{k+1}$ would do the job, as $|(\xi_{k+1}, x_i)|\ge|(\xi_k, x_i)| - \frac{\delta}{2}|(x_{k+1}, x_i)|\ge \frac{\delta}{2}$.
This is similar to what @Carl_Schildkraut did, but with an analysis flavor.