A left-invariant vector field on a Lie group $G$ satisfies
$$ (L_g)_*X = X $$
for all $g\in G$. So we have in particular $\omega(X_p)=(L_{g^{-1}})X_p=X_e$ with $\omega$ the Maurer-Cartan form on $G$.
Please have a look at this derivation of the Maurer-Cartan equation. It says that if $X$ and $Y$ are left-invariant vector fields, then they satisfy
$$\tag{1}X(\omega(Y))=Y(\omega(X))=0$$
Why is that true? I only get
$$ X(\omega(Y))=X(Y)=[X,Y] $$
so
$$ X(\omega(Y))-Y(\omega(X))=X(Y)-Y(X)=[X,Y]-[Y,X]=2[X,Y] $$
You should start from the Cartan Formula which is $$d\omega(X,Y)=X(\omega(Y))-Y(\omega(X))-\omega([X,Y])$$ Then since $X(\omega(Y))$ and $Y(\omega(X))$ are $0$ then you have $$d\omega(X,Y)+\omega([X,Y])=0.$$
In fact $\omega(Y)$ is a constant since $Y$ is left-invariant. If $\omega(Y)$ is a constant then whatever derivativeyou will apply you will obtain $0$. Being more precise if you have a vector field $X$ which at the end of the story is some kind of derivative and therefore you have $$X(\omega(Y))=0$$.