I am seeking a motivation for the definition of the curvature of a plane curve. How did people come with the idea of the definition of the curvature? Below I am more specific.
The fundamental theorem for plane curves states the following. Giving two curves $\alpha$ and $\beta$ there exists a rigid motion $M:\mathbb R^2\to \mathbb R^2$ such that $\beta(t)=M(\alpha(t))$ if, and only if, the curves $\alpha$ and $\beta$ have the same curvature function.
Assume for a moment that you do not know about the curvature and that you would like to classify plane curves up to rigid motions. How could one come up with the idea of a geometric invariant that is enough to distinguish curves?
The derivative tells you the tangent line, which is the best linear approximation to a curve near a point.
With the second derivative you can find the osculating circle - the circle that best approximates the curve near a point. The curvature is the inverse of its radius. That's a pretty natural geometric invariant.
If these together did not suffice to determine the curve up to a rigid motion you'd look for more invariants.