Which Topological Groups Have a Unique Group Structure (up to isomorphism)?
I know that there are many non-isomorphic finite groups of same order, so there are many group structures possible for discrete finite sets under discrete topology (in which case all functions will be continuous).
On the other hand $\Bbb R$ and $S^1$ seem to have a unique group structure (addition and complex multiplication). (also see Group Structure on $\Bbb R$)
So, basically what i want to know is that if $(X,.)$ and $(Y,.)$ are topological spaces with group operations $.$ then under what assumptions is it true that if $X$ is homeomorphic to $Y$(as a topological space) then $X$ isomorphic to $Y$(as a group)?
This isn't really an answer, but it's too long for a comment. In any case, I think the answer could depend on your formulation. I can see two ways to interpret your question. Suppose $X$ and $Y$ are topological groups, homeomorphic as topological spaces. Are they necessarily isomorphic as
Obviously 2 implies 1. I think the second question is the more interesting one. I don't know if this fact will lead to an answer, but all separable (infinite dimensional) Banach spaces are homeomorphic as topological spaces. They are isomorphic as real vector spaces for cardinality reasons I believe, thus as abstact groups, but I don't think they are isomorphic as topological groups (this is just my guess.)
One further remark is that your remark on discrete topological groups carries over to discrete topological groups of any cardinality. So $\Bbb Z$ and $\Bbb Q$, both endowed with the discrete topology, are isomorphic as topological spaces, but aren't isomorphic as groups. Maybe this is an indication that the good context for your question isn't abstract topological groups but connected topological groups, or even connected Lie groups.