Let $\mathfrak{R}= ⟨\mathbb{R},<,+,-,\cdot,0,1⟩$ be the standard model of $Th(\mathbb{R})$ in the language of ordered fields. I need to show that there exists a (non standard) model of $Th(\mathbb{R})$ with the same cardinality of $\mathbb{R}$ but not isomorphic to $\mathfrak{R}$.
My doubts are on how to prove the "not-isomorphic" part, so I'll just sketch my proof of existence of a model:
Let's expand the language adding a new constant $c_x$ for each $x \in \mathbb{R}$ and an additional new constant $c$. We consider the following set of formulas:
$$ \Gamma = Th(\mathbb{R}) \cup \{c_x \ne c_y\}_{x,y \in \mathbb{R}, x \ne y} \cup \{c_x < c\}_{x \in \mathbb{R}}$$
We can show $\Gamma$ is finitely satisfiable, thus, by Compactness Theorem, satisfiable, thus it has a model with cardinality $\kappa \ge |\mathbb{R}|$. By the Löwenheim-Skolem Downward theorem it has a model of cardinality $c = |\mathbb{R}|$, say $^*\mathfrak{R}$.
Now my doubts are how to show that $^*\mathfrak{R} \not \cong \mathfrak{R}$. I guess the lack of an isomorphism should be showed after shrinking back the structures to the original language, i.e. removing all the constant symbols. Moreover, as the two models have the same cardinality we cannot simply conclude there is not a bijection, so I think a possible proof is assume there is such an isomorphism and get a contradiction with the order relation, but all my reasonings in this direction seem at a dead point. How can one show there is not such an isomorphism?
As has been pointed out in comments, we do not need to add a constant symbol for every element of $\mathbb{R}$. Let $L$ be the usual first-order language for ordered fields. Extend $L$ to $L'$ by adding a constant symbol $c$. Let $T$ be the set of all sentences of $L$ true in the reals, under the usual interpretation. Make a new theory $T'$ by adding to $T$ the axioms $1\lt c$, $1+1\lt c$, $(1+1)+1\lt c$, and so on.
Then, as pointed out in the OP, the theory $T'$ is consistent, and therefore has a model $M$ of cardinality equal to the cardinality of $\mathbb{R}$. The sentences $1\lt c$, $1+1\lt c$, $(1+1)+1\lt c$, and so on, are true in $M$. It follows that there is an element $c_M$ of $|M|$ (the underlying set of $M$) such that $1_M\lt_M c_M$, $(1+1)_M\lt_M c_M$, and so on. Now to be technical we should let $M'$ be $M$ restricted to the language $L$. Then $|M'|$ contains an object, namely $c_M$, such that the inequalities $1_{M'}\lt_{M'} 1_{M'}$, and so on, hold.
Finally, we show there is no order isomorphism of $\mathbb{R}$ and $M'$. For let $\phi: \mathbb{R}\to M'$ be such an isomorphism, and suppose that $\phi(K)=c_M$. Since the reals are an Archimedean ordered field, there is a positive integer $n$ such that the interpretation of $1+1+\cdots +1$ ($n$ times) in $\mathbb{R}$ is greater than $K$.
Note that $\phi$ takes the interpretation of $1+1+\cdots+1$ in $\mathbb{R}$ to its interpretation in $M'$. Since $\phi$ is order-preserving, it follows that the interpretation of $1+1+\cdots +1$ ($n$ times) in $M'$ is greater (in $M'$) than $c_M$. But this is not the case.