If $T$ is a self-adjoint linear map on a $n$-dimensional inner product space $X$ (either real or complex) then we know by the spectral theorem that there is an orthonormal basis of $X$, call it $v = \{v_1, v_2, \dots, v_n\}$, under which the matrix of $T$ is diagonal.
Even though this is not true for arbitrary linear maps, we can still do something. In fact, by the singular value decomposition, $T$ is still guaranteed to have a diagonal matrix if we are willing to use two different orthonormal bases for $X$, call them $e = \{e_1, e_2, \dots, e_n\}$ and $f = \{f_1, f_2, \dots, f_n\}$.
At first, I thought that if we performed a SVD to a self-adjoint operator, then we would get, up to a reordering, $v = e = f$ and the same diagonal matrices.
Actually this is not true, because the SVD is even stronger that that: the elements of the diagonal matrix are positive!
So I am left wondering if there exists a less strong SVD where the elements of the diagonal matrix are not constrained to be positive, so that if we performed this decomposition to a self-adjoint operator we would get the same of an eigenvalue-eigenvector decomposition..
I think the question turns on how much information the singular values $\sigma_i$ carry for an operator which may not be normal.
Suppose we want to factor $T = U \Gamma V^*$, and we're allowed to choose $\Gamma$ diagonal with non-positive (or even non-real) entries. The entries would have to have moduli $|\gamma_i | = \sigma _i$ in some ordering, by an argument I'll give below. And beyond that, I'm not sure what kind of canonical choice we could make for the arguments of the $\gamma_i$.
We know what $U$ and $V$ have to be: if $T: W \to W$ is a complex linear operator and $T = U \Gamma V^*$ for $\Gamma$ diagonal, then $T^*T = V \Gamma^* \Gamma V^*$. This has to be the orthogonal diagonalization of the positive operator $T^* T$, so $V$ must be the eigenvectors for $T^* T$. By a similar argument $U$ must be the eigenvectors for $TT^*$. And we can see that $\overline {\gamma_i}{\gamma_i} = |\gamma_i|^2 $ have to be the eigenvalues of $T^* T$, so we know the modulus of $\gamma_i$. But which argument for $\gamma_i$ do we choose, if not zero? In order to get what you're asking for, we'd like to make some choice that reflects something about the original operator $T$ (like, say, something to do with its eigenvalues). But I'm not sure what that would be.