One-point compactification of $S_{\Omega}$ is homeomorphic with $\bar S_{\Omega}$.
Let $X$ be a topological space. Then the One-point compactification of $X$ is a certain compact space $X^*$ together with an open embedding $c : X \to X^*$ such that the complement of $X$ in $X^*$ consists of a single point, typically denoted $\infty$.
Let $X$ be a well-ordered set. Given $\alpha \in X$, let $S_{\alpha}$ denote the set $S_{\alpha} = \{x \mid x \in X \text{ and }x < \alpha \}$. It is called the section of $X$ by $\alpha$.
I am finding difficulty to do the problem!
Consider $\bar{S_\Omega}$ with its order topology. Since $S_\Omega$ is a locally compact and $T_2$ space and $\bar{S_\Omega}$ is a $T_2$ and compact space it is enough to prove that $\bar{S_\Omega} - \{\Omega\} \cong S_\Omega$ to prove that it is homeomorphic to its one-point compactification. (By your notation I guess you're using Munkres book, this is Theorem 29.1. This is the same result Henno is mentioning in his comment.)
Define the natural embedding $c:S_\Omega\to\bar{S_\Omega}$ considering both spaces with the order topology. It's easy to show that $c$ is a homeomorphism to its image ($\bar{S_\Omega} - \{\Omega$}).