$$ \frac{1}{121} = 0.00\ \overbrace{8264}\ \overbrace{4628}\ 09\ \overbrace{91735}\ \overbrace{53719} \ldots $$ The entire $22$-digit repetend appears here. It begins with the first digit after the decimal point. The sequence $8264$ gets reversed and appears as $4628$, and then the same happens with $91735$. But the $09$ between those two doesn't fit any such pattern that I've noticed.
Can anything intelligent be said about this? Is it an instance of some phenomenon that has other instances? Where is it mentioned in the literature?
Try looking at it like this: $$ \frac{1}{121} = 0.0\ \overbrace{08264}^a\ \overbrace{46280}^\bar a\ 9\ \overbrace{91735}^b\ \overbrace{53719}^\bar b\ 0\ 08264 \ldots $$ It becomes much more obvious what's going on if you look at it with this patterning. Notice that $a+b=99999$ and $\bar a+\bar b=99999$, while $a$ and $\bar a$, and $b$ and $\bar b$, are digit-reversals of each other. The remaining two digits sum to 9, naturally.