The point of intersection of the tangents at the points $P(\theta_1)$ and $Q(\theta_2)$ on the circle $x^2+y^2=a^2$ are $$ x=\frac{a\cos(\frac{\theta_1+\theta_2}{2})}{\cos(\frac{\theta_1-\theta_2}{2})}\;;\;y=\frac{a\sin(\frac{\theta_1+\theta_2}{2})}{\cos(\frac{\theta_1-\theta_2}{2})}\\ $$
$$ \vec{PQ}\perp \vec{OC}\implies \bigg<a(\cos\theta_1-\cos\theta_2),r(\sin\theta_1-\sin\theta_2)\bigg>\cdot<x,y>=0\\ -2ax\sin(\frac{\theta_1+\theta_2}{2}\sin(\frac{\theta_1-\theta_2}{2}))+2ay\cos(\frac{\theta_1+\theta_2}{2}\sin(\frac{\theta_1-\theta_2}{2}))=0 $$ but it is not leading to anywhere and I really don't see any hint on how to approach the problem ?

The slopes of OP and OQ are $\tan\theta_1$ and $\tan\theta_2$, respectively. Given that $P=a(\cos\theta_1,\sin\theta_1)$ and $Q=a(\cos\theta_2,\sin\theta_2)$, the equations for the two tangent lines PC and QC are,
$$ (y-a\sin\theta_1) = -\frac{1}{\tan\theta_1}(x-a\cos\theta_1)$$ $$ (y-a\sin\theta_2) = -\frac{1}{\tan\theta_2}(x-a\cos\theta_2)$$
After simplification,
$$ x\cos\theta_1 + y \sin\theta_1 =a$$ $$ x\cos\theta_2 + y \sin\theta_2 =a$$
Then, just solve for the intersection to obtain,
$$x= a\frac{\sin\theta_2-\sin\theta_1}{\sin(\theta_2-\theta_1)}=a\frac{\cos\frac{\theta_1+\theta_2}{2}}{\cos\frac{\theta_1-\theta_2}{2}}$$ $$y= a\frac{\cos\theta_2-\cos\theta_1}{\sin(\theta_2-\theta_1)}=a\frac{\sin\frac{\theta_1+\theta_2}{2}}{\cos\frac{\theta_1-\theta_2}{2}}$$