Can there be such a thing as positive and negative complex numbers? Why or why not?
What about positive or negative imaginary numbers?
It seems very tempting to say $+5i$ is a positive number while $-2i$ is a negative number. On an Argand diagram (complex plane) $+5i$ would be represented by a point above the horizontal axis while $-2i$ is a point below the horizontal axis.
You may turn $\mathbb{C}$ into a totally ordered set and then define $a \geq b$ if and only if $a-b \geq 0$. An example of such a total order on $\mathbb{C}$ is the lexicographic order defined on $\mathbb{R}^2$.
The problem is that if you do so, then when you restrict this new order to $\mathbb{R}$ as a subset of $\mathbb{C}$ and you expect it to satisfy the field order axioms, this order will not agree with the usual ordering on $\mathbb{R}$. So, you can't think of this order as an extension of the order we have on $\mathbb{R}$.
In fact it is not possible to define an order on $\mathbb{C}$ that interacts with addition and multiplication the same way that elements of $\mathbb{R}$ do. This is because that by accepting the field order axioms on $\mathbb{R}$, you can prove that $\forall x \in \mathbb{R}: x^2 \geq 0$, while this theorem breaks in $\mathbb{C}$ because $i^2 < 0$.