Let $k$ be an algebraically closed field with positive characteristic $p>0$ and let $1<q_1<q_2<q_3$ be its powers. Let $X\subset \mathbb{P}^4$ be given by $(1:t:t^{q_1}:t^{q_2}:t^{q_2+1}+t^{q_1+q_3})$. Then $X$ has orders $0,1,q_1,q_2,q_2+1$ i.e. there exist hyperplanes that have this intersection multiplicity with the curve.
The fact that the orders $0,1$ are correct comes from the fact that every curve has such intersection multiplicities. My problem is that I am unable to prove the rest formally. My guess would be that the hyperplane $X_2=0$ has intersection multiplicity $q_1$ with $X$ at the point $(1:0:0:0:0)$, however, I can't come up with a proof.
I would greatly appreciate your help!
The intersection multiplicity of a curve $C\subset\Bbb P^n$ and a hyperplane $H$ at a point $c\in C$ is defined to be the length of $\mathcal{O}_{C,c}/(h|_C)$ as a module over the local ring $\mathcal{O}_{C,c}$, where $h$ is a local equation for $H$ and $h|_C$ is its restriction to $C$. In your case, taking $c$ to be the point corresponding to $t=0$, the local ring $\mathcal{O}_{C,c}$ is a DVR with uniformizer $t$, and the hyperplane $V(x_i)$ restricts to the $i$th coordinate of your embedding. This means you can just read off the length from the lowest exponent present in each coordinate:
Note that these are local invariants associated to a specific point in a specific embedding - at other points or under different embeddings of the same abstract curve, you might get different numbers.