On the Wikipedia page $16$ Pythagorean triples with $c \leq 100$ are listed:
$$(3, 4, 5), (5, 12, 13), (8, 15, 17), (7, 24, 25), (20, 21, 29), (12, 35, 37), (9, 40, 41), (28, 45, 53), (11, 60, 61), (16, 63, 65), (33, 56, 65), (48, 55, 73), (13, 84, 85), (36, 77, 85), (39, 80, 89), (65, 72, 97)$$
I noticed that of these $16$ primitive Pythagorean triples $a+b$ is prime in $14$ cases, only the cases $a+b=9+40=49$ and $a+b=39+80=119$ are not primes.
Are there some available computational results much beyond $c \leq 100$ that would confirm intuition that really $a+b$ is almost-always a prime number or this is just some instance of the rule that this is a small sample so it is not quite unusual to have this high percentage of primes?
I have been running some programs. It seems that the break even point, where the possible values of your $a+b$ are half prime and half composite for $$ a+b < 1736495 \; , \; $$ a number between one million and two million. I'm impressed. There seems to be a little wobble, up to 1,740,000 I think sometimes there are more primes, sometimes more composite. I guess I know some good ways to investigate that a bit more.
The following may or may not make any sense, but shows that we can take a + b < 1736495 as our break even point.
ORIGINAL:
The number you are asking about, for a primitive Pythagorean triple, is $$ n^2 + 2nm - m^2 $$ when $\gcd(m,n) = 1$ and they are not both odd. The usual way to talk about this is to take integrs $x,y$ with $x = n + m$ and $y = m,$ so we still have $\gcd(x,y) = 1$ and now $x$ is odd. Finally $$ a+b = x^2 - 2 y^2 . $$ Since $x,y$ are coprime, and $x$ is odd, this number can be divisible only by primes $$ p \equiv \pm 1 \pmod 8. $$ The first few such primes are $$7, 17 , 23 , 31, 41, 47, 71 , 73, 79, 89, 97, 103, 113, 127, 137, 151, 167, 191, 193, 199, 223, ... $$ The two smallest products of these primes are $49$ and $119.$ You have seen both. Those are as small as possible.