So I'm going through "Elementary Topology Problem Textbook" by Viro and all, and have problems with 23.3x paragraph which is devoted to simplicial schemes. More concretely I can't tackle 23.4x problem which is also on an attached image. My thoughts on that are:
So (open) simplex is just a set $ \{ c \in S : Supp(c) = \sigma\} $, where $\sigma \in \Sigma$. I know that open sets in $S(V,\Sigma)$ are just open balls $ B_r(c) := \{ c' \in S(V,\Sigma) : \rho(c,c') < r \} $ and closed balls are $ B_r(c) := \{ c' \in S(V,\Sigma) : \rho(c,c') \le r \} $. By that I can conclude that $c' \in B_r(c) $ iff $ \sigma_{c'} \subseteq \sigma_c $ (but I can't work through that correctly, I've done this step on my own feelings).
Can anyone give me a hint how to tackle this problem, I feel like I either misunderstood something or can't see an obvious step. Thanks.

What is called a simplicial scheme in your book is usually denoted as an abstract simplicial complex. See https://en.wikipedia.org/wiki/Abstract_simplicial_complex. The space $S(V,\Sigma)$ is the geometric realization. You can give it the metric topology as in your book, but normally it is endowed with the so-called weak topology.
Some remarks concerning the definition in your book:
Usually one requires that the elements of $\Sigma$ are finite non-empty subsets of $V$. It is perhaps questionable whether on wants to consider the empty set as a simplex (I do not think it makes sense), but that is a minor issue. The major distiction is that your book allows simplices which are infinite subsets of $V$. I doubt that this makes sense, but "definitions are free".
The "intersection condition" is redundant because each subset of an element of $\Sigma$ belongs to $\Sigma$.
The support of a function $c : V \to I$ such that $\sum_{v \in V} c(v) = 1$ can be at most countable, otherwise $\sum_{v \in V} c(v)$ would be divergent. This means that simplices which are uncountable sets do not have a geometric realization. This indicates that it does really make no sense to admit arbitrary subsets of $V$ as simplices.
Given $\sigma \in \Sigma$, the set $\lvert \sigma \rvert = \{c : V \to I \mid \text{Supp}(c) \subset \sigma, \sum_{v \in V} c(v) = 1 \}$ is called the closed simplex associated to $\sigma$ or the geometric realization of $\sigma$. The open simplex associated to $\sigma$ is defined as the set $\lvert \sigma \rvert^\circ = \{c : V \to I \mid \text{Supp}(c) = \sigma, \sum_{v \in V} c(v) = 1 \}$. Let us give a simple example. If $\sigma = \{v_0,v_1\}$, then the set $\lvert \sigma \rvert$ is nothing else than set of functions $c_t : V \to I$, $t \in I$, such that $c_t(v_0) = t, c_t(v_1) = 1-t$ and $c_t(v) = 0$ else. The function $t \mapsto c_t$ gives a bijection between $I$ and $\lvert \sigma \rvert$. It is easy to see that this is a homeomorphism if $\lvert \sigma \rvert$ is endowed with the metric topology. Under this identification $\lvert \sigma \rvert^\circ$ corresponds to the open interval $(0,1)$. For $\sigma = \{v_0,v_1,v_2\}$ the space $\lvert \sigma \rvert$ can similarly be identified with a triangle (= geometric $2$-simplex) which is the convex hull of three points $v'_0,v'_1,v'_2$ in general position in some $\mathbb R^n$. Each point in the convex hull has the form $\sum_{i=0}^2t_iv'_i$ with $t_i \in I$ and $\sum_{i=0}^2t_i = 1$. Each function $c \in \lvert \sigma \rvert$ is identified with the point $\sum_{i=0}^2c(v_i)v'_i$. Also see the Appendix.
I recommend to consult also another textbook, for example
Spanier, Edwin H. Algebraic Topology. Springer Science & Business Media, 1989.
Note that always
a) $\lvert \sigma \rvert^\circ \subset \lvert \sigma \rvert$
b) $ \lvert \sigma \rvert \subset \lvert \tau \rvert$ if $\sigma \subset \tau$.
Your question is completely answered by the following:
The set $\lvert \sigma \rvert$ is closed in $S(V,\Sigma)$: Consider a sequence of points $c_n$ in $\lvert \sigma \rvert$ which converges to some $c \in S(V,\Sigma)$. For $v \notin \sigma$ we have $c_n(v) = 0$, thus $c(v) = \lvert c(v) - c_n(v) \rvert \le \rho(c,c_n)$ which shows $c(v) = 0$ because $\rho(c,c_n)$ becomes arbitrarily small. Thus $\text{Supp}(c) \subset \sigma$ which means $c \in \lvert \sigma \rvert$.
Define $\dim(\sigma) = n$ if $\sigma$ contains $n+1$ elements (= vertices). Then $\lvert \sigma \rvert^\circ = \lvert \sigma \rvert$ if and only if $\dim(\sigma) = 0$: If $\dim(\sigma) = 0$, i.e. $\sigma = \{ v \}$, then both $\lvert \sigma \rvert^\circ, \lvert \sigma \rvert$ contain precisely the function $\delta_v$ given by $\delta_v(v) =1, \delta_v(w) = 0$ for $w \ne v$. If $\dim(\sigma) = n > 0$, then $\sigma = \{v_0,\ldots, v_n\}$. The functions $\delta_{v_i}$ belong to $\lvert \sigma \rvert$, but not to $\lvert \sigma \rvert^\circ$.
$\lvert \sigma \rvert$ is the closure of $\lvert \sigma \rvert^\circ$: Let $c \in \lvert \sigma \rvert$, where $\sigma = \{v_0,\ldots, v_n\}$. Define $b : V \to I, b(v) = 1/(n+1)$ for $v \in \sigma$ and $b(v) = 0$ else. Then $b \in \lvert \sigma \rvert^\circ$ and for $m \in \mathbb N$ the functions $c_m = (1-2^{-m})c +2^{-m}b$ belong to $\lvert \sigma \rvert^\circ$. We have $$\rho(c,c_m) = \sup_{v \in V} \lvert c(v) - c_m(v) \rvert = \max_{i=0,\ldots,n} \lvert 2^{-m}c(v) - 2^{-m}b(v) \rvert \le 2\cdot 2^{-m} ,$$ thus $c_m \to c$ which shows that $c$ is contained in the closure of $\lvert \sigma \rvert^\circ$.
Thus an open simplex is closed if and only if its dimension is $0$.
If $\Sigma$ contains a simplex $\tau \supsetneqq \sigma$, then $\lvert \sigma \rvert^\circ$ is not open: Let $c \in \lvert \sigma \rvert^\circ$ and $\epsilon > 0$. We have $\lvert \sigma \rvert^\circ \subset \lvert \sigma \rvert \subset \vert \tau \rvert$, thus $c$ is contained in the closure of $\subset \vert \tau \rvert^\circ$. Choose $c' \in \vert \tau \rvert^\circ$ such that $\rho(c,c') < \epsilon$. We have $\text{Supp}(c') = \tau$, thus $c' \notin \lvert \sigma \rvert^\circ$. This shows that no open ball $B_\epsilon(c)$ can be contained in $\lvert \sigma \rvert^\circ$.
If $\Sigma$ contains no simplex $\tau \supsetneqq \sigma$, then $\lvert \sigma \rvert^\circ$ is open: Let $c \in \lvert \sigma \rvert^\circ$, where $\sigma = \{v_0,\ldots, v_n\}$. We have $c(v_i) > 0$. Let $\epsilon = \min c(v_i)$. We claim that $B_\epsilon(c) \subset \lvert \sigma \rvert^\circ$. So let $c' \in B_\epsilon(c)$, i.e. $\rho(c,c') < \epsilon$. Then $\lvert c(v_i) - c'(v_i) \rvert \le \rho(c,c') < \epsilon$ which is impossible if $c'(v_i) = 0$. Let $\tau = \text{Supp}(c') \in \Sigma$. We have shown that $\sigma\subset \text{Supp}(c') = \tau$, hence by assumption $\sigma = \tau$. Thus $c' \in \lvert \sigma \rvert^\circ$.
Appendix:
The geometric realization of a simplicial scheme (abstract simplicial complex) is defined as the set of all functions $c : V \to I$ such that $\text{Supp}(c)$ is a simplex in $\Sigma$ and $\sum_{v \in V} c(v) = 1$. Equivalently it can be defined as the set of all functions $c : V \to \mathbb R$ such that $\text{Supp}(c)$ is a simplex in $\Sigma$, $c(v) \ge 0$ for all $v$ and $\sum_{v \in V} c(v) = 1$.
Define an $\mathbb R$-vector space $$\ell^\infty(V) = \{f : V \to \mathbb R \mid \sup_{v \in V} \lvert f(v) \rvert < \infty \}$$ and give it the norm $\lVert f \rVert_\infty = \sup_{v \in V} \lvert f(v) \rvert $. Then Viro's set $S = S (V,\Sigma)$ is a subset of $\ell^\infty(V)$ which receives its metric by $\rho(c,c') = \lVert c - c' \rVert_\infty$.
For each $v \in V$ let $\delta_v : V \to \mathbb R, \delta_v(v) = 1$ and $\delta_v(w) = 0$ else. The set of these $\delta_v$ is a linearly independent subset of $\ell^\infty(V)$. For each $f \in \ell^\infty(V)$ with finite support we have $f = \sum_{v \in V}f(v)\delta_v$. Note that $\sum_{v \in V}f(v)\delta_v$ is actually a finite sum since $f(v) = 0$ for almost all $v$.
For $\dim(\sigma) = n < \infty$, $\sigma = \{v_0,\ldots,v_n\}$, the closed simplex $\lvert \sigma \rvert$ is nothing else than the convex hull of the $n+1$ basis vectors $\delta_{v_0},\ldots,\delta_{v_n}$, i.e. an $n$-dimensional simplex in the $n+1$-dimensional real vector space spanned by $\delta_{v_0},\ldots,\delta_{v_n}$. To see this let $c \in \lvert \sigma \rvert$ and $t_i = c(v_i)$. Then $t_i \ge 0$, $\sum_{i=0}^n t_i = 1$ and $c = \sum_ {v \in V} c(v) \delta_v = \sum_{i=0}^n t_i\delta_{v_i}$ since $\text{Supp}(c) \subset \sigma$.
For $\dim(\sigma) = \infty$ (if that is admitted as a simplex), this no longer true: The convex hull of $B(\sigma) =\{ \delta_v \mid v \in \sigma \}$ is a strict subset of $\lvert \sigma \rvert$ since there are functions $c \in \lvert \sigma \rvert$ with infinite support.
The sets $\lvert \sigma \rvert$ are always closed (see the proof above) and for $\dim(\sigma) = \infty$ one can easily show that $\lvert \sigma \rvert$ is the closure of the convex hull of $B(\sigma)$.
What about open simplices $\lvert \sigma \rvert^\circ$ with infinite dimension (i.e. with an infinite set $\sigma$)?
If $\sigma$ is an uncountable set, then $\lvert \sigma \rvert^\circ$ is empty. This is due to the fact that an uncountable sum of positive real numbers (which we can interpret as the supremum over all finite subsums) cannot be $< \infty$.
If $\sigma$ is a countable infinite set, $\sigma = \{v_n \mid n \in \mathbb N\}$, then $\lvert \sigma \rvert^\circ$ is non-empty. For example, the function $c$ given by $c(v_n) = 2^{-n}$ and $c(v) = 0$ for $v \notin \sigma$ is in $\lvert \sigma \rvert^\circ$. However, it is never an open subset. In fact, it is not even open in the subspace $\lvert \sigma \rvert$. For each $C \in \lvert \sigma \rvert^\circ$ and each $\epsilon > 0$ the open ball $B_\epsilon (c)$ contains an element of $\lvert \sigma \rvert \setminus \lvert \sigma \rvert^\circ$. I leave this as an exercise.