Using the identity
\begin{align}
n \ \text{mod} \ k = n - k \lfloor \tfrac{n}{k} \rfloor,
\end{align}
one has
\begin{align}
\sum_{k = 1}^{n} (n \ \text{mod} \ k) =\sum_{k = 1}^{n} n - k \lfloor \tfrac{n}{k} \rfloor = n^{2} - \sum_{k = 1}^{n} k \lfloor \tfrac{n}{k} \rfloor.
\end{align}
Finally, since
\begin{align}
\sum_{k = 1}^{n} k \lfloor \tfrac{n}{k} \rfloor = \sum_{k = 1}^{n} \sigma(k),
\end{align}
the claim follows.
Using the identity \begin{align} n \ \text{mod} \ k = n - k \lfloor \tfrac{n}{k} \rfloor, \end{align} one has \begin{align} \sum_{k = 1}^{n} (n \ \text{mod} \ k) =\sum_{k = 1}^{n} n - k \lfloor \tfrac{n}{k} \rfloor = n^{2} - \sum_{k = 1}^{n} k \lfloor \tfrac{n}{k} \rfloor. \end{align} Finally, since \begin{align} \sum_{k = 1}^{n} k \lfloor \tfrac{n}{k} \rfloor = \sum_{k = 1}^{n} \sigma(k), \end{align} the claim follows.