$E$ is a three digit number so
$$\begin{align*}E &= 100a+10b+c\\ &= 99a+a+9b+b+c\\ &=(99a+9b)+(a+b+c)\\ &=3(33a+3b)+(a+b+c) \end{align*}$$
If $E$ is divisible by $3$ then the sum of its digits must also be divisible by $3$.
How does the last equation prove this?
"How does the last equation prove this?"
I number $n$ divides $m*n + k$ if and only if $n$ divides $k$. If $n$ divides $k$ than it will divide $m*n + k$ because that's a multiple of $n$ more. As if $n$ doesn't divide $k$ then $n$ won't divide $m*n + k$ because .... that's a multiple of $n$ more.
So, $3$ divides $33(33a + b)$ and so $3$ divides $33(33a+b) + (a+b+c)$ if and only if $3$ divides $a+b+c$.