My intuitive understanding is the following:
Kan extensions are the closest "approximation" of a given functor, that factors along a given functor. What's happening is that left adjoints preserve colimits, so this guarantees the existence of the Kan extension of the composition. So since $\mathcal{L}$ is the 'closest' functor to $\mathcal{L}$, we should have, $$\text{Lan}_\mathcal{F} (\mathcal{L}\circ \mathcal{G})\cong\mathcal{L}\circ \text{Lan}_\mathcal{F} \mathcal{G}.$$ So I was expecting this.
Now for the proof, the idea I felt was to apply Yoneda in some way. So, $$\text{Hom}_{\mathcal{D}^{\mathcal{B}}}(\mathcal{L}\text{Lan}_{\mathcal{F}}\mathcal{G},\mathcal{K}) \cong \text{Hom}_{\mathcal{C}^{\mathcal{B}}}(\text{Lan}_{\mathcal{F}}\mathcal{G},\mathcal{R}\mathcal{K})\cong\text{Hom}_{\mathcal{C}^{\mathcal{A}}}(\mathcal{G},\mathcal{R}\mathcal{K}\circ \mathcal{F})\cong \text{Hom}_{\mathcal{D}^{\mathcal{A}}}(\mathcal{L}\mathcal{G},\mathcal{K}\mathcal{F})$$ Doesn't this already say, by precomp-left Kan adjointness, that $\text{Lan}_{\mathcal{F}}(\mathcal{L}\circ \mathcal{G})\cong \mathcal{L}\circ \text{Lan}_\mathcal{F} \mathcal{G}$? In the usual books they assume $\mathcal{K}=\mathcal{L}\text{Lan}_{\mathcal{F}}\mathcal{G}$, and make some arguments I don't understand.


The fact that left adjoints preserve left Kan extensions can be motivated in many ways according to the generality you are forced to work in.
Your argument is a viable solution provided there exists a "left Kan extension along $F$" functor, which by uniqueness of adjoints must be a left adjoint to precomposition with $F$. This is not always the case; it is the case when the left extensions you are considering are pointwise, and strictly speaking this is a less general concept than the bare definition of Kan extension with its 2-dimensional universal property.
Left adjoint 1-cells of any 2-category, however, preserve left Kan extensions, and this can be deduced quite swiftly from some basic 2-category theory. If you feel you might need this more general argument, I'll update my answer.