This is my attempt to prove that, if $a > 0$, then $\frac{1}{a} > 0$, using just field and order axioms.
$$a > 0 \implies a \cdot \left(\frac{1}{a}\right)^2 > 0 \cdot \left(\frac{1}{a}\right)^2 \implies a \cdot \left(\frac{1}{a}\right)^2 > 0 \implies a \cdot \left(\left(\frac{1}{a}\right) \cdot \left(\frac{1}{a}\right)\right) > 0$$
By associativity of multiplication:
$$\left(a \cdot \left(\frac{1}{a}\right)\right) \cdot \left(\frac{1}{a}\right) > 0$$
We know that $a \cdot \left(\frac{1}{a}\right) = 1$, because one is the multiplication inverse of the other.
So we have:
$$1 \cdot \left(\frac{1}{a}\right) > 0 \implies \frac{1}{a} > 0 $$
Which is what we wanted to prove.
My question are:
In the field axioms, there's no axiom that says that $0$ times another number is $0$, but I have used this property. How would you translate it to field and order axioms?
I have assumed that $\left(\frac{1}{a}\right)^2$ is positive, have you noticed? Note that I need a positive number in order not to change the $>$ sign. But this is not present in the field or order axioms. How would you explain this?
$x\cdot 0 = x\cdot (0+0) = x\cdot 0 + x\cdot 0$, now add $-(x\cdot 0)$ on both sides
If $x>0$ then $x\cdot x>x\cdot 0=0$. If $x<0$, then $0<-x$, hence $x\cdot x=(-x)\cdot(-x)>(-x)\cdot 0=0$ (I assume you already know $(-x)(-y)=xy$). Only if $x=0$, we do not have $x\cdot x>0$. So you need to show $\frac1a\ne 0$.
You can simplify your overall proof anyway: Given $a>0$, assume than not $\frac 1a>0$. Then either $\frac 1a=0$, hence $1=a\cdot \frac1a=a\cdot 0=0$, contradiction. Or $\frac1a<0$, then $0<-\frac 1a$, hence $-1=a\cdot(-\frac1a)>0$, then also $1=(-1)(-1)>0$, leading to $0=1+(-1)>0$, contradiction. Of course this argument also relies on similar basic "standard" results about fields.