The property is $$\sum_{d|n}\phi(d) = n$$
And the proof provided is
If $d$ divides $n$, let $C_d$ be the unique subgroup of $\mathbb{Z}/n\mathbb{Z}$ of order $d$, and let $\Phi_d$ be the set of generators of $C_d$. Since all elements of $\mathbb{Z}/n\mathbb{Z}$ generate one of the $C_d$, the group $\mathbb{Z}/n\mathbb{Z}$ is the disjoint union of the $\Phi_d$ and we have
$$n = \text{Card}(\mathbb{Z}/n\mathbb{Z}) = \sum_{d|n}\text{Card}(\Phi_d) = \sum_{d|n}\phi(d)$$
But I can't prove to myself the uniqueness of the subgroups to let the rest fall together.
As I understand your question, you need to prove in $\Bbb Z/n\Bbb Z$, there is a unique subgroup of order $d$ where $d|n$. Suppose, $m\in\Bbb Z/n\Bbb Z$, then $|m|$,the order of $m$, is $n/(n,m)$. So, if a subgroup $H$ has order $d$, then it is generated by $m$ where $n/(n,m)=d$. Clearly $m=n/d$ is such a number. Any other such number must be a multiple of $n/d$, hence all possible generators of a group of order $d$ belong to the same subgroup.