Let $X$ be the 2-dimensional CW complex where 2-cells are glued as follows:

The goal is to prove/disprove that $X$ is a manifold. Here's my attempt to disprove this.
Suppose $X$ is a manifold. In particular, $X$ is a closed 2-dimensional manifold.
Since $H_2(X) \cong \mathbb Z$, it follows that $X$ is orientable. Therefore, by Poincare duality, $H^1(X) \cong H_1(X) \cong G$, where $G$ is the abelian group generated by five elements $a, b, c, d, e$ satisfying $a+b+c+d+e = 0$.
By Universal coefficient theorem, $H^1(X)$ must be a free abelian group, and so $G$ must be also free. Then, I attempted to show that $G$ has a non-zero torsion element which would yield a contradiction.
I would appreciate any hint or help with proving/disproving this statement.
Your space $X$ is indeed a 2-dimensional manifold.
There is a general theorem in 2-dimensional topology which goes like this:
It's not too hard to see that $2$-cells of $X$ correspond one-to-one with the given polygons, and the $1$-cells correspond one-to-one with the given edge pairs.
The hardest part of the proof of this theorem is to identify the $0$-cells of the CW structure on $X$, and to verify that the image in $X$ of each vertex of the polygon collection has a 2-manifold neighborhood. The proof requires an understanding of "vertex cycles". The 0-cells of the CW structure will correspond one-to-one with the vertex cycles. And for each vertex in the quotient, a disc neighborhood of that vertex is obtained by gluing together "circular sector neighborhoods" of the elements of the associated vertex cycle.
In this example, the ten vertices form a single vertex cycle, which you can see as follows.
Start with the upper vertex of the left polygon, and label it by the unordered pair $\{e+,a-\}$ meaning that it is the terminal vertex of a certain $e$ edge and the initial vertex of an $a$ edge.
To walk to the next step of the vertex cycle, look for another vertex with label $a-$: that would be the upper vertex of the right polygon, labelled $\{a-,c+\}$ (it is the initial vertex of an $a$ edge and the terminal vertex of a $c$ edge).
Next, look for another vertex with label $c+$: that would be the lower left vertex of the left polygon, labelled $\{c+,d-\}$.
Continuing this process, one gets the vertex cycle \begin{align*} &\{e+,a-\}, \{a-,c+\}, \{c+,d-\}, \{d-,a+\}, \{a+,b-\},\\ &\{b-,d+\}, \{d+,e-\}, \{e-,b+\}, \{b+,c-\}, \{c-,e+\}, \\ &\{e+,a-\} \end{align*} which is a length $10$ vertex cycle, starting at and returning to the upper vertex of the left pentagon labelled $\{e+,a-\}$. So, the single vertex of the quotient has a 2-disc neighborhood formed by gluing together $10$ circular sector neighborhoods in a circular pattern, one such sector neighborhood for each of the $10$ vertices of the diagram.