The question:
Prove $\forall k\geq 4,\log(1+x_k)-x_k\leq {-1\over6k}$ where $x_k={(-1)^k\over\sqrt k}$.
The above inequality holds iff $$\begin{align} &\log(1+x_k)\leq x_k-{1\over 6k}\\ &\Leftrightarrow 1+x_k\leq \exp (x_k-{1\over6k}) \end{align}$$ Using $$x+1\leq e^x$$we get $$x_k+1\leq e^{x_k}$$
$log(1+x) - x$ corresponds to the error of a first-order approximation of $log(1+x)$, so this will be least where the second (and higher) derivatives are least, which is on the positive side of 0. This means we can ignore the alternating signs and prove $\frac{1}{\sqrt{k}} - log(1+\frac{1}{\sqrt{k}}) \geq \frac{1}{6k}$.
The series for $log(1+x)$ is $x - \frac{x^2}{2} + \frac{x^3}{3} - ...$, which means we must have $\frac{1}{2k} - \frac{1}{3k^{3/2}} + \frac{1}{4k^2} - ... \geq \frac{1}{6k}$, or $\frac{1}{3k} \geq \frac{1}{3k^{3/2}} - \frac{1}{4k^2} + ...$
But the RHS is less than $\frac{1}{3k^{3/2}}$ for any $k \geq 1$, so the inequality definitely holds in the required range.