Let $\mathcal{B}$ denote the collection of all $\epsilon$-neighborhoods in $\mathbb{R}^m$ whose radius $\epsilon$ is rational and whose center has all coordinates rational.
I'm tryin to prove that (1) $\mathcal{B}$ is countable and that (2) every open subset of $\mathbb{R}^m$ can be expressed as the countable union of members of $\mathcal{B}$ .
(1) I get that all epsilon balls in $\mathcal{B}$ are centered on members of $\mathbb{Q}^n$. Is it possible to proceed by saying that $\mathcal{B}$ has the same cardinality as $\mathbb{Q}^{n+1}$?? Because the additional coordinate could denote $\epsilon$.
(2) I intuitively understand why the second part is true but I am having difficulty proving it.
(1) To your first point, yes you can absolutely say that $\mathcal{B}$ has the same cardinality as $\mathbb{Q}^{n+1}$. One way to do so is using the very natural bijection you had in mind to make such a suggestion. Map the first $n$ coordinates of $v\in\mathbb{Q}^{n+1}$ to the center of an open ball in $\mathcal{B}$, and map the last coordinate to the radius. Since $\mathbb{Q}^{n+1}$ is countable, so is $\mathcal{B}$.
(2) A standard trick is to let an open ball $B\in\mathbb{R}^n$ be given. Then, if $v$ is a point in $B$, there exists some $b_v\in\mathcal{B}$ so that $b_v\subseteq B$ and $v\in b_v$. That open ball $B$ is then just the union $\bigcup_{v\in B}b_v$. Since every open set in $\mathbb{R}^n$ is some arbitrary union of open balls (or empty), and since every open ball is a union of elements in $\mathcal{B}$, it follows that every open set is a union of elements of $\mathcal{B}$. That union is countable since $\mathcal{B}$ is countable.
Demonstrating the existence of $b_v$ can be done by considering the minimum distance from $v$ to the boundary of $B$. There is a rational center less than half that distance from $v$, and you can choose a rational radius large enough to encompass $v$ but small enough to stay within $B$. You can use thirds or other smaller fractions instead of halves if you don't want to think about technical details.