Prove that there will be at least one even number in the sum of odd numbered digit and its reverse,if the number of digits is of the form $4n+1$.
If the number of digits is of the form $4n+3$ ,there exist number whose sum of the number and its reverse contains all odd numbers.
$$\sum_{i=0}^{n-1}{10^i(d_i+d_{n-i-1})} = \sum_{i=0}^{m-1}{10^i(2x_i+1)}$$ $$d_i \in\left\{0, 1, 2, 3, 4, 5, 6, 7, 8, 9\right\}$$ $$x_i \in\left\{0, 1, 2, 3, 4\right\}$$ $$m \in\left\{n, n+1\right\}$$
Let $m=n+b, b\in\left\{0, 1\right\}$
$$\sum_{i=0}^{n-1}{10^i(d_i+d_{n-i-1})} = \sum_{i=0}^{n+b-1}{10^i(2x_i+1)}$$
$$\sum_{i=0}^{n-1}{10^i(d_i+d_{n-i-1}-2x_i-1)} = \begin{cases}0 & b=0\\10^n(2x_n+1) & b = 1\end{cases}$$
$$\sum_{i=0}^{n-1}{10^i(d_i+d_{n-i-1}-2x_i-1)} = 10^n(2x_n+1)b$$
Because the carry of the sum of two numbers is always 1 or 0,
$$\sum_{i=0}^{n-1}{10^i(d_i+d_{n-i-1}-2x_i-1)} = 10^nb$$
Let $y_i=d_i+d_{n-i-1}-2x_i-1$
$$\sum_{i=0}^{n-1}{10^iy_i} = 10^nb$$
By the fact that $2x_i+1$ is the sum of $d_i+d_{n-i-1} \bmod 10$
$$2x_i+1 = d_i+d_{n-i-1}+p_i \bmod 10 = d_i+d_{n-i-1}+p_i-10q_i$$
$$p_i, q_i\in\left\{0, 1\right\}$$
$$y_i = 10q_i-p_i \in\left\{-1, 0, 9, 10\right\}$$
$n$ is odd, so let $n=2k+1$
$$y_i = d_i+d_{2k-i}-2x_i-1$$
For $i=k$
$$y_k = 2(d_k-x_k)-1 \in \left\{-1, 9\right\}$$
For $i=k+t, -k \leq t \leq k$
$$y_{k+t} = d_{k+t}+d_{k-t}-2x_{k+t}-1$$
$$y_{k+t}-y_{k-t} = 2(x_{k+t}-x_{k-t})$$
Consider the range of $x_i$
$$-8 \leq y_{k+t}-y_{k-t} \leq 8$$
Consider all possible values of $y_i$
$$y_{k+t} = y_{k-t}$$
All $10^i$ terms must be canceled out, except for $i=n$, so we have following rules.
Now replace $i$ by $k+t$ and $k-t$, and assume $t\geq 0$.
If $y_{k+t}=9$ for some $t$, because $y_{2k}=y_0\in\left\{0, 10\right\}$ would never be 9, it is sure that $t\neq k$, then $$y_{k+t-1}=y_{k-t+1}=y_{k+t+1}=y_{k-t-1}=9$$
This will make $y_{i}=9$ for all $i$, which violates $\exists j<k-t$ such that $y_j=10$.
So no $y_i$ could be 9. We can simply the rules.
We already know that $y_k=-1$, so
If $t$ is odd, then
$$y_{k+t}=10$$
If $t$ is even, then
$$y_{k+t}=-1$$
We know that $y_0 = 10$, because no term will cancel it if $y_0 = -1$, so k is odd.
Let $k = 2v+1$ $$n=2k+1=4v+3$$