For $k_2 \geq k_1 > 0$ and $d\geq 1$, I need to show that $$ k_1\tanh(k_1d) + k_2\tanh(k_2d) - 2\sqrt{k_1k_2\tanh(k_1d)\tanh(k_2d)} \leq (k_2-k_1)\tanh((k_2-k_1)d). $$
I've started by letting $$ f(k) = \sqrt{k\tanh(kd)}$$ so that the problem can be written as $$ f(k_2) - f(k_1) \leq f(k_2 - f_1), $$ and then set $k_2 = k_1 + a$ for some $a\geq0$ so I need to show that $$ g(k_1) = f(k_1 + a) - f(k_1) - f(a) \leq 0. $$
I've differentiated $g(k_1)$ w.r.t $k_1$ with the intent of showing it to be $\leq 0$ with a maximum value of $0$ when $k_1=0$. Numerically it seems feasible but I'm struggling to show it analytically. Explicitly, $$g'(k_1) = \dfrac{(k_1+a)d+\tanh((k_1+a)d)[1 - (k_1+a)d\tanh((k_1+a)d)]}{2\sqrt{(k_1+a)\tanh((k_1+a)d)}} - \dfrac{k_1d+\tanh(k_1d)[1 - k_1d\tanh(k_1d)]}{2\sqrt{k_1\tanh(k_1d)}} \leq 0.$$
Is this a good way of going about the proof? Any alternative ideas would be appreciated.
Without loss of generality $d=1$, and you want to prove $f(x):=\sqrt{x\tanh x}\implies f(x+y)\le f(x)+f(y)$. We only need verify the case $x,\,y\ge 0$, since $f$ is even and $f(x+y)=f(|x+y|)\le f(|x|+|y|)$. Since $g(x):=\frac{f(x)}{x}=\sqrt{\frac{\tanh x}{x}}$ is decreasing on $\Bbb R^+$ (you may find it easier to check this property for $g^2$), $f(x+y)=(x+y)g(x+y)\le xg(x)+yg(y)=f(x)+f(y)$.