I need to show that $ x^{1/3} < \frac{1}{3}x + \frac{2}{3} \forall x \in (0,1)$. I have been given the hint to consider the expression $\frac{1}{3}x - x^{1/3}$, but the Taylor Series centred at $x=0$ vanishes after only a two terms.
Do I have to centre the distribution about a different real number?
Of course. $x^{\frac 1 3}$ has a vertical tangent in $x=0$, that's precisely why you are getting infinite derivatives.