This is my working so far:
$$e^{ix} + e^{-ix} = 0$$
$$e^{-ix}\left(e^{2ix}+1\right) = 0$$
Therefore,
$$e^{2ix} = -1\implies e^{ix} = i$$
$$ix = \log(i)\implies ix = i\left(2\pi k + \frac\pi2\right)$$
Hence,
$$x = 2\pi k + \frac\pi2$$ (where $k$ is an integer)
I do not understand why it is $\pi k$ and not $2\pi k$
This is not correct. You could also have $e^{ix} = -i$, which is where your missing solutions are.