I was just checking to see if I wsa doing this right, as it isn't a formal proof. Just showing the identity.
Let $U(r) \hat{r}$ b a vector in spherical coordinates. Given that the vector is only dependent on r, and there's no $\hat{\phi}$ or $\hat{\theta}$ component, that means that in the usual formula for the curl in spherical coordinates: $$\nabla \times U(r)\hat{r} = \hat{r} \frac{1}{\sin \theta}\left[\frac{\partial}{\partial\theta}(u_{\phi}\sin\theta) - \frac{\partial u_{\theta}}{\partial\theta} \right]+ \hat{\theta} \frac{1}{r}\left[\frac{1}{\sin \theta}\frac{\partial u_r}{\partial\phi}- \frac{\partial}{\partial r}(ru_{\phi}) \right]+\hat{\phi} \frac{1}{r}\left[\frac{\partial}{\partial\phi}(ru_{\theta})- \frac{\partial u_r}{\partial r}\right]$$
the $u_{\theta}$ and $u_{\phi}$ are just zero, since the original function has only a radial component. Since they go to zero all those partial derivatives go to zero, correct?
If $U(r)$ is scalar function and you want to show that $\vec F(r) = U(r)\hat r$ has zero curl. Than easiest way to do this is: $$ \int_0^r U(s) ds = V(r) $$ $$ U(r) \hat r = V'(r)\hat r = \nabla V(r) $$ but $$ \text{curl } \text{grad } V(r) = 0 $$