I am trying to prove that $\mathbb{R}/\mathbb{Z}$ under addition is isomorphic to $S^1$. The definitions I have to work with are: \begin{align*} \mathbb{R}/\mathbb{Z} & = [0,1) \text{ with addition mod $1$} \\ S^1 & = \{z \in \mathbb{C}^{*} \mid |z| = 1\} \text{ with multiplication.} \end{align*} Though it seems natural to use the first isomorphism theorem, I don't yet have access to it, so I need to use the bijection $t \mapsto \exp(2 \pi i t)$. Here is my attempt at a proof.
Define $\varphi: \mathbb{R}/\mathbb{Z} \to S^1$ by $\varphi(t) = \exp(2 \pi i t)$. We first show that $\varphi$ is a homomorphism.
Homomorphism. Let $a,b \in \mathbb{R}/\mathbb{Z}$. We denote addition in $\mathbb{R}/\mathbb{Z}$ by $*$ and addition in $\mathbb{R}$ by $+$. If $a + b < 1$, then $a * b = a + b$, and we have \begin{align*} \varphi(a * b) & = \varphi(a + b) \\ & = \exp^{2 \pi (a + b) i} \\ & = \exp(2 a \pi i + 2 b \pi i) \\ & = \exp(2 a \pi i) \exp(2 b \pi i) \\ & = \varphi(a) \varphi(b). \end{align*} Now suppose that $a + b \geq 1$. Then $a*b = a + b - 1$, and we have \begin{align*} \varphi(a * b) & = \varphi(a + b - 1) \\ & = \exp(2 \pi (a + b - 1) i) \\ & = \exp(2 \pi a i + 2 \pi b i - 2 \pi i) \\ & = \exp(2 \pi a i) \exp(2 \pi b i) \exp(-2 \pi i) \\ & = \varphi(a) \cdot \varphi(b) \cdot 1 \\ & = \varphi(a) \varphi(b), \end{align*} so $\varphi$ is a bijective homomorphism and therefore an isomorphism.
We next show that $\varphi$ is a bijection of sets.
Injectivity. For injectivity, we show that $\mathrm{ker}(\varphi) = \{0\}$. For any $t \in [0,1)$, we have \begin{align*} t \in \mathrm{ker}(\varphi) & \iff \varphi(t) = \exp(2 \pi i t) = 1 \\ & \iff \cos(2\pi) + i \sin(2\pi t) = 1 + 0i \\ & \iff \sin(2 \pi t) = 0 \\ & \iff t \in \mathbb{Z} \cap [0,1) \\ & \iff t = 0, \end{align*}
so $\mathrm{ker}(\varphi) = \{0\}$, so $\varphi$ is injective.Surjective. Let $z \in S^1$, and write $z$ in its exponential form $z = \exp^{i \theta}$ where $\theta \in [0,2\pi)$. As $0 \leq \theta < 2\pi$, we have $0 \leq \frac{1}{2\pi} \theta < 1$, so $\frac{1}{2\pi} \theta \in \mathbb{R}/\mathbb{Z}$. We then have $$ \varphi\left(\frac{1}{2\pi} \theta\right) = \exp\left(2\pi \cdot \frac{\theta}{2\pi} i \right) = \exp(i \theta) = z, $$ so $\varphi$ is surjective and therefore bijective.
Well it's true that you cannot "use" the first isomorphism theorem. But there is no harm in proceeding like the proof of the first isomorphism theorem.
Define $q:\Bbb{R\to R/Z}$ by $q(x) = (x-\lfloor x\rfloor) +\Bbb{Z}$ . This is just the quotient map which is sending a real number to it's coset representative.
This map is clearly surjective as for any $y+\Bbb{Z}$ such that $y\in[0,1)$ we can take the pre-image to be $y\in\Bbb{R}$.
Define $f:\mathbb{R}\to S^{1}$ by $f(x)=e^{2i\pi x}$ .
Then it is easy to verify that this is a homomorphism.
Define the map $\bar{f}:\Bbb{R}/\Bbb{Z}\to S^{1}$ such that $\bar{f}(x+\Bbb{Z})=f(x)=e^{2i\pi x}$.
Now we need to see if this map is well-defined.
if $x+\Bbb{Z}=y+\Bbb{Z}$. Then $x-y\in\Bbb{Z}$ so let $x=y+n$ for some $n\in\Bbb{Z}$.
Then we have $\bar{f}(x+\Bbb{Z})=\bar{f}((y+n)\Bbb{Z})=e^{2i\pi (y+n)}=e^{2i\pi y}\cdot e^{2i\pi n} =e^{2i\pi y}=\bar{f}(y+\Bbb{Z})$.
So this is well defined.
Now if $x+\Bbb{Z},y+\Bbb{Z} \in \Bbb{R}/\Bbb{Z}$ then
$$\bar{f}((x+\Bbb{Z})+(y+\Bbb{Z}))=\bar{f}(x+y+\Bbb{Z})=f(x+y)=e^{2i\pi(x+y)}$$
$$=e^{2i\pi x}\cdot e^{2i\pi y}=\bar{f}(x+\Bbb{Z})\cdot \bar{f}(y+\Bbb{Z})$$
and hence $\bar{f}$ is a group homomorphism.
Now you have already correctly verified that $\ker{\bar{f}}=\Bbb{Z}$ which is the identity in $\Bbb{R}/\Bbb{Z}$. and it is surjective as $f$ and $q$ are surjective. In otherwords you can find $\frac{\theta}{2\pi}\in \Bbb{R}$ such that $\bar{f}(\theta+\Bbb{Z})=f(\theta)=e^{i\theta}\in S^{1}$.
Hence this is an isomorphism.
Note that we are implicitly using the Universal Propert of Quotients. That is $q$ and $f$ uniquely yields a homomorphism $\bar{f}$ such that $\bar{f}\circ q=f$. In fact you need not even verify the surjectivity of $\bar{f}$ as the surjectivity of $f$ and $q$ guarantee it due to the universal property of quotients.