I want to show that for a manifold $M$ and smooth map $\varphi:M\rightarrow GL(n,\mathbb{R})$ we have $\varphi^*\omega=\varphi^{-1} d\varphi$.
The Maurer-Cartan form is defined as for $X\in T_gG$ we have $\omega(X)=d_g(L_{g^{-1}})(X)$. My idea to approach this probblem was to first show that for a matrix Lie group the Maurer-Cartan form is given by $g^{-1}dg$ and then statment $\varphi^*\omega=\varphi^{-1} d\varphi$ should somehow follow.
First question: To show that $\omega(X)=d_g(L_{g^{-1}})(X)$ agrees with $g^{-1}dg$. For a matrix group $L_h$ is a linear operaion so $d_g(L_h)=L_h$ and then $\omega(X)=L_{g^{-1}}(X)=g^{-1}(X)$. But how do we get $dg$ into this?
Second question: Does $\varphi^*\omega=\varphi^{-1} d\varphi$ follow from $g^{-1}dg$ and if so how?
This can be done by some simple manipulation with your definitions:
\begin{eqnarray*} (\varphi^*\omega)_p(X_p) & = & \omega_{\varphi(p)}(\varphi_*X_p) \\ & = & d_{\varphi(p)}\left (L_{\varphi(p)^{-1}} \right ) d\varphi_p(X_p) \\ & = & \left . \frac{d}{dt} \right |_{t=0} L_{\varphi(p)^{-1}} \cdot \varphi(\gamma(t)) \\ & = & \varphi(p)^{-1}\left [\left . \frac{d}{dt} \right |_{t=0} \varphi(\gamma(t)) \right ] \\ & = & \varphi(p)^{-1}d\varphi_p(\gamma'(t)) \end{eqnarray*}
where we take $\gamma(t)$ to be the integral curve of $X$ with initial point $p$.