I am unclear what is meant here with the notation $\mathbb{Z}(...)$ and 'extends linearly over $\mathbb{Z}$'. I'm reading this paper 'embedded homology of hypergraphs and applications', and admittedly I don't have a strong formal background here, I'm willing to learn though! Here is the example they give:
A standard n-simplex is denoted as
$$\Delta^n = \{v_0,...,v_n\}.$$
The $(n-1)$-faces of the standard n-simplex $\Delta^n$ are denoted as
$$\Delta_i^{n-1} = \{ v_0,...,\hat{v}_i,...,v_n \}, 0 \leq i \leq n$$
We have the face maps $d_i$ sending $\Delta^n$ to $\Delta_i^{n-1}$, for $0 \leq i \leq n$. And we have the boundary maps
$$\partial_n:\mathbb{Z} \to \mathbb{Z}(\Delta_0^{n-1},...,\Delta_n^{n-1})$$
given by $\partial_n = \sum_{i=0}^n(-1)^id_i$, which extends linearly over $\mathbb{Z}$. The power set of $\Delta^n$ is denoted as $\Delta[n]$, called the standard simplicial complex spanned by $n+1$ vertices.
For any set $S$, the free abelian group on $S$, denoted as $\mathbb Z(S)$, is defined to be the set of all finite sums$^\color{blue}*$ $x = n_1s_1 + \cdots + n_ks_k$, where $k \in \mathbb Z^+$, $n_i \in \mathbb Z$ and $s_i \in S$, with the same $+$ as operation. It has the property that for any abelian group $G$ and any function $f : S \to G$ there exists a unique group homomorphism $\widetilde{f\,}\! : \mathbb Z(S) \to G$ that extends $f$ (i.e. $\widetilde{f\,}\!(s) = f(s)$ for all $s \in S$), namely, $$\widetilde{f\,}\!(n_1s_1 + \cdots + n_ks_k) = n_1f(s_1) + \cdots + n_kf(s_k).$$ We say that $\widetilde{f\,}$ is obtained from $f$ by extending it linearly over $\mathbb Z$, and sometimes $\widetilde{f\,}$ is also denoted by the same symbol $f$.
In your case, the function $\partial_n : \Delta^n \to \mathbb Z(\Delta_0^{n-1},\dots,\Delta_n^{n-1}) := \mathbb Z(\Delta_0^{n-1} \cup \cdots \cup \Delta_n^{n-1})$ given by $v \mapsto \sum_{i=0}^n (-1)^id_i(v)$ extends linearly over $\mathbb Z$ to a homomorphism $\partial_n : \mathbb Z(\Delta^n) \to \mathbb Z(\Delta_0^{n-1},\dots,\Delta_n^{n-1})$.
$^\color{blue}*$Formally, $\mathbb Z(S)$ consists of functions $x : S \to \mathbb Z$ such that $\{s \in S : x(s) \neq 0\}$ is finite, with pointwise addition. Note then that, for each $s \in S$, the function (which I will denote by the same letter $s$) that sends $s$ to $1$ and everything else to $0$ is an element of $\mathbb Z(S)$; and so, for each $x \in \mathbb Z(S)$ we have that $x$ is a finite linear combination of "elements" in $S$: $$x = \sum_{s \in S}x(s)s.$$