(1) Let $f$ be a continuous function on $[0,1]$. Then for every partition $P$ of $[0,1]$, the lower and upper Riemann sums of $f$ over $P$ satisfy $L(f,P)\neq U(f,P)$.
(2) Let $f:[0,\infty)\to\mathbb{R}$ be a continuous function such that $\lim_{x\to\infty}f(x)=0$. Then $f$ has a maximum value on $[0,\infty)$.
For (1), I think the answer is False because a continuous function on a closed interval is integrable, and the definition of integrability is that the upper and lower Riemann sums are within $\epsilon>0$ of each other, and thus can be equal. However, I do not know for sure what the correct answer is.
For (2), the correct answer is False, but I cannot understand why. I can see how it would be false if the domain of $f$ was $(0,\infty)$ instead, because then $f(x)=1/x$ is a counterexample, but since the interval is closed on the left, and $f$ is continuous, I don't see how $f$ could fail to have a maximum value and still be continuous. Even more confusing, according to my professor the statement would be True if $f$ were positive.
In regards to your response for 1, the definition of integrability does NOT mean that the upper and lower partition sums are equal. The definition states that for every $\epsilon > 0$ there is a $\delta > 0$ such that $U(f,P)-L(f,P) < \epsilon$ whenever the maximum width of an interval in $P$ is less than $\delta$.
For instance, if $f(x) = x$ and $P = \{0,\tfrac{1}{2},1\}$, then the upper sum would be $U(f,P) = \displaystyle\sum_{i = 1}^{2}\left[\max_{x_{i-1} \le x \le x_i}f(x)\right](x_i-x_{i-1}) = f(\tfrac{1}{2}) \cdot (\tfrac{1}{2}-0) + f(1) \cdot (1-\tfrac{1}{2}) = \tfrac{1}{2} \cdot \tfrac{1}{2} + 1 \cdot \tfrac{1}{2} = \tfrac{3}{4}$,
while the lower sum would be $L(f,P) = \displaystyle\sum_{i = 1}^{2}\left[\min_{x_{i-1} \le x \le x_i}f(x)\right](x_i-x_{i-1}) = f(0) \cdot (\tfrac{1}{2}-0) + f(\tfrac{1}{2}) \cdot (1-\tfrac{1}{2}) = 0 \cdot \tfrac{1}{2} + \tfrac{1}{2} \cdot \tfrac{1}{2} = \tfrac{1}{4}$
So $U(f,P)$ and $L(f,P)$ don't have to be equal.
However, the question asks if $U(f,P) \neq L(f,P)$ is always true. Can you exhibit an example where $L(f,P) = U(f,P)$?
For 2, consider a function such as $f(x) = -\dfrac{1}{x+1}$. Clearly, $\displaystyle\lim_{x \to \infty}f(x) = 0$. But does $f$ attain a maximum on $[0,\infty)$?