The real line with the countable complement topology is not compact.
I create an open cover of $\mathbb R$ by: Let $\mathbb Q$ denote the rationals. Let an open cover be defined be the set of $\mathbb Q-\{q\} $, where $q \in \mathbb Q$. Then this set is countable. I am unsure how to proceed from here. And is this a good example of an open cover that doesn't have a finite subcover? Which will lead to my conclusion of not compact?
Without even going so far as using rational numbers, what about this counter example: Define the open set $X_i = \mathbb{R}-\mathbb{N}+\{i\}$ with $i\in \mathbb{N}$. $\cup_{i\in\mathbb{N}}X_i$ is an open cover of $\mathbb{R}$ with no finite subcover.