I have been reading Gelfand theory for a while and it just occurs to me that the whole theory is an analogy to what we did for Banach spaces.
For a Banach space $X$, we investigate its dual $X'$ and double dual $X''$. Some times these spaces give us information about $X$, eg. the embedding of $X$ in $X''$ gives notions such as reflexivity.
In Gelfand theory, we impose more algebraic structure on the space, namely, the object is algebras $A$. Now the dual space become the spectrum $\sigma(A)$ and the embedding becomes the Gelfand transformation $\Gamma:A\to C(\sigma(A))$.
Thus I wonder whether there is similar notion like reflexivity, that is, $\Gamma(A)=C(\sigma(A))$ and whether this gives some information about the algebra.
I have not gotten time to look into this problem myself. But intuitively such case should be rare for each step in $A\to\sigma(A)\to\Gamma(A)$ we lose some thing more than in the case for Banach spaces. But if $\Gamma(A)=C(\sigma(A))$ for some special $A$, it seems to tell a lot.
Thanks!
Here is a more detailed list of properties of Gelfand's transformation, which shows us necessary conditions for algebra $A$ to be isometrically isomorphic to $C_0(\Omega(A))$
Theorem (A. Ya. Helemskii, Banach and locally convex algebras)
Let $\Gamma:A\to C_0(\Omega(A))$ be Gelfand's transformation of commutative Banach algebra $A$, then
Theorem (D. P. Blecher, C. Le Merdy, Operator algebras and their modules. An operator space approach)
Let $A$ be a $C^*$-algebra, $B$ a Banach algebra and $\pi: A\to B$ a contractive homomorphism. Then $\pi(A)$ is a norm closed and it possesses an involution with respect to which it is a $C^*$-algebra. Moreover $\pi$ is then a $*$-homomorphism into $C^*$-algebra. If $\pi$ is one-to-one then $\pi$ is an isometry.
Thus if we assume that $\Gamma:A\to C_0(\Omega(A))$ is an isometric isomorphism we see that $A$ can be endowed with involution which makes it a $C^*$-algebra. Moreover $\Gamma$ becomes an isometric $*$-isomorphism.
The main result here that if $A$ is a commutative Banach algebra and $\Gamma$ is an isometric isomorphism then $A$ can be made a $C^*$ algebra and, moreover now $\Gamma$ preserves additional structure - involution.