Is it possible to draw some parallels between the Wronskian and the Gram matrix? Could they be used for solving the same problem? What is the principal difference between them?
The Gram matrix of a set of vectors $v_{1},\cdots ,v_{n}$ in an inner product space is the Hermitian matrix of inner products, whose entries are given by $G_{ij}=\langle v_{i},v_{j}\rangle$. A set of vectors is linearly independent if and only if the Gram determinant (the determinant of the Gram matrix) is non-zero.
For $n-1$ times differentiable functions $f_1, \cdots , f_n$ the Wronskian $W(f_1, \cdots , f_n)$ as a function is defined by $$ {W(f_{1},\ldots ,f_{n})(x)={\begin{vmatrix}f_{1}(x)&f_{2}(x)&\cdots &f_{n}(x)\\f_{1}'(x)&f_{2}'(x)&\cdots &f_{n}'(x)\\\vdots &\vdots &\ddots &\vdots \\f_{1}^{(n-1)}(x)&f_{2}^{(n-1)}(x)&\cdots &f_{n}^{(n-1)}(x)\end{vmatrix}}} $$ If the functions $f_i$ are linearly dependent, then so are the columns of the Wronskian as differentiation is a linear operation, so the Wronskian vanishes.
Both constructions are of the form $\det(D)$ for
$$ D = \begin{pmatrix} \varphi_1(v_1) & \varphi_1(v_2) & \dots & \varphi_1(v_n) \\ \vdots & \vdots & \ddots & \vdots \\ \varphi_n(v_1) & \varphi_n(v_2) & \dots & \varphi_n(v_n) \end{pmatrix}. $$
where $v_1,\dots,v_n \in V$ are vectors and $\varphi_i \in V^{*}$ are linear functionals on $V$. For the first case, we have $\varphi_i(v) = \left< v, v_i \right>$ while in the second case we have $\varphi_i(f) = f^{(i-1)}(x)$. Another example of this construction is the (transpose of the) Vandermonde determinant for which $v_1 = 1, v_2 = x, \dots, v_n = x^{n-1}$ and $\varphi_i(f) = f(\alpha_i)$.
Set $U = \operatorname{span} \{ v_1, \dots, v_n \}$. This construction is useful for various reasons:
Beyond this similarity, there are important differences between the various cases: