My question arose while studying something about Kan Extensions.
We know that we have the following diagram
$$ \begin{array}{ccc} &&\mathsf{\Delta} & \xrightarrow{\mathcal{F}} & \mathsf{Top}\\ &&\mathcal{y} \searrow& & \nearrow Lan_{\mathcal{y}\mathcal{F}}\\ &&& \mathsf{sSet}, &&&& \end{array} $$ where $Lan_{\mathcal{y}\mathcal{F}}$, stands for the left Kan Extension of $\mathcal{F}$ along the Yoneda Embedding $\mathcal{y}$, of the simplex category $\mathsf{\Delta}$ into the category of its presheaves. Now, because the category of topological spaces is co-complete and the simplex category is small we know the left Kan Extesnsion exists. However for $\mathcal{F}$ being the functor $$[n] \mapsto |\Delta^n|,$$ we get a rather well-known functor denoted by $|-|$, called geometric realization, which is left adjoint of the singularization functor, $$ S : \mathsf{Top} \rightarrow \mathsf{sSet} \\ \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, Y \mapsto S_Y = \mathsf{hom}_\mathsf{Top}( \mathcal{F}[-],Y).$$ Now, because of the particular structure these categories possess, means that the right Kan Extension of $\mathcal{F}$ along the Yoneda Embedding $\mathcal{y}$ does exist as well, and moreover we have a certain adjunction of the form $Lan_{\mathcal{y}} \dashv - \circ \mathcal{y} \dashv Ran_{\mathcal{y}}.$ With all the above it is clear what the left Kan extension is, however I'm not sure about the right one. Can you explain what is this functor? (If I haven't done something wrong so far :))
Also for the first adjunction I mentioned, $|-| \dashv S$, is there any categorical theoretic insight (an argument arising from Kan Extension theory for instance) that imposes these functors being adjoints?
It's an odd duck, this right Kan extension, and trivial more often than you might think! Skip to the end of this long answer to see examples.
Call the right Kan extension you're after $R : \mathsf{sSet} \to \mathsf{Top}$. Using the formula for the Kan extension as an end, you get that for any simplicial set $X$, $$R(X) = \int_{[n]\in\mathsf\Delta} |\Delta^n|^{\mathsf{hom}_\mathsf{sSet}(X, \Delta^n)}.$$
Now look at that exponent, $\mathsf{hom}_\mathsf{sSet}(X, \Delta^n)$. The simplicial set $\Delta^n$ is the nerve of the category $[n]$, which is the poset $0 \le 1 \le 2 \le \cdots \le n$ thought of as a category in the usual way. The nerve functor $N : \mathsf{Cat} \to \mathsf{sSet}$ has a left adjoint $\tau_1 : \mathsf{sSet} \to \mathsf{Cat}$ (called the fundamental category functor). So we get a natural bijection $\mathsf{hom}_\mathsf{sSet}(X, \Delta^n) \cong \mathsf{hom}_\mathsf{Cat}(\tau_1 X, [n])$.
This shows that $R(X)$ only depends on $\tau_1X$, say $R = R' \circ \tau_1$, where $R' : \mathsf{Cat} \to \mathsf{Top}$ is the right Kan extension of your functor $\mathcal{F} : \mathsf\Delta \to \mathsf{Top}$ along the functor $\mathsf\Delta \to \mathsf{Cat}$ that sends $[n] \in \mathsf\Delta$ to the category we also called $[n]$. As an end, $$R'(C) = \int_{[n]\in\mathsf\Delta} |\Delta^n|^{\mathsf{hom}_\mathsf{Cat}(C, [n])}.$$
Now another similar round of simplification: this category $[n]$ is a preorder and the inclusion $\mathsf{Pre} \to \mathsf{Cat}$ of preorders into categories has a left adjoint: associated to a category $C$ there is a preorder $C^\mathrm{pre}$ whose elements are the objects of $C$ and where $x \le y$ if there is a morphism $x \to y$ in $C$. We have a natural bijection $\mathsf{hom}_\mathsf{Cat}(C, [n]) \cong \mathsf{hom}_\mathsf{Pre}(C^\mathrm{pre}, [n])$, where that last $[n]$ denotes the obvious poset. Again we can factor $R' = R'' \circ (-)^\mathrm{pre}$ and write $R'''$ as a right Kan extension.
In fact, the inclusion of posets into preorders also has a left adjoint, so we can further simplify! Given a preorder $P$, the relation $\sim$ given by $x \sim y \iff (x \le y \text{ and } y \le x)$ is an equivalence relation and the quotient $P/\!\!\sim$ becomes a partial order by defining $[x] \le [y] \iff x \le y$.
So, all told, we get that $R(X)$ only depends on the poset $P(X):=(\tau_1X)^\mathrm{pre}/\!\!\sim$, and is given by the formula $$R(X) = \int_{[n]\in\mathsf\Delta} |\Delta^n|^{\mathsf{hom}_\mathsf{Poset}(P(X), \Delta^n)}.$$ It's probably a good idea to pause and describe this poset more directly. The elements of the poset are equivalence classes of 0-simplices of $X$, where two 0-simplices $x$ and $y$ are equivalent if there exists a directed path of 1-simplices from $x$ to $y$ and also a directed path of 1-simplices from $y$ to $x$. In the poset we have $[x] \le [y]$ if there exists a directe path of 1-simplices from $x$ to $y$ (this does not depend on the representatives $x$ and $y$). Notice, in particular that $P(X)$ only depends on the 1-skeleton of $X$.
OK, now some examples!
$R(\Delta^n) = |\Delta^n|$, because right Kan extension along a fully faithful functor (here, the Yoneda embedding $y$) really extends the functor $\mathcal{F}$. Since $P(\Delta^n) = [n]$, this means that whenever $P(X) = [n]$, we get $R(X) = |\Delta^n|$. For example any $X$ that is a subsimplicial set of $\Delta^n$ containing the spine (the path $0 \to 1 \to \cdots \to n$) has $R(X) = |\Delta^n|$.
If $X$ has the property that for any $0$-simplices $x$ and $y$ there is a directed path of 1-simplices from $x$ to $y$ (and thus also one from $y$ to $x$, then $P(X)$ has only one element and thus $R(X)$ is a point. Examples of this include any simplcial set with only one 0-simplex, and any connected Kan complex.
Added later: You can simplify that last description down to a finite limit. Given a poset $P$, let $\mathcal{S}_P$ be the category with objects order-preserving surjective functions of the form $P \to [n]$, and morphisms from $\lambda : P \to [m]$ to $\mu : P \to [n]$ be surjective order-preserving maps $\alpha : [m] \to [n]$ with $\alpha \circ \lambda = \mu$. There is a functor $F_P : \mathcal{S}_P \to \mathsf{Top}$ given by $F_P(P \to [n]) = |\Delta^n|$. Then this space we're after is just $\tilde{R}(P) = \lim F_P$.
If $P$ is a finite poset, then this finite limit is a convex subpolytope of a big product of simplices, and is not hard to compute in small examples.