Here is example $7)$, pp. $59$ of Kechris' book "Classical Descriptive Set Theory":
Let $S_\infty$ be the group of permutations of $\mathbb{N}$. With the relative topology as a subset of $\mathcal{N}=\Bbb{N}^{\Bbb{N}}$ (Baire space), it is a topological group and it is a Polish group since $S_\infty$ is a $G_\delta$ set in $\mathcal{N}$ ... Again, $S_\infty$ is not locally compact.
I want to prove the above facts. This is my attempting:
(i) $S_\infty$ is $G_\delta$: let $INJ=\{(x_n)\mid injective\}$ and $SURJ=\{(x_n)\mid surjective\}$. Then clearly $S_\infty=INJ\cap SURJ.$ Let us prove that they are $G_\delta$:
$x\in SURJ\iff\forall n\exists m\colon=x(m)$ and hence $$SURJ=\bigcap_n\bigcup_m \Bbb{N}^{n-1}\times \{n\}\times \Bbb{N}^{\Bbb{N}-n}.$$ Moreover $x\in INJ\iff \forall n,m (n\ne m\implies x_n\ne x_m)\iff \forall n,x_n\in \Bbb{N}^{\Bbb{N}}\setminus (\bigcup_{i=1}^{n-1}\pi_i(i))$ open, where $\pi_i\colon \Bbb{N}^{\Bbb{N}}\to \Bbb{N}$ is the $i$th-projection. Hence $$INJ=\bigcap_n [\Bbb{N}^\Bbb{n-1}\times (\Bbb{N}\setminus \bigcup_{i=1}^{n-1}\pi_i(i))\times \Bbb{N}^\Bbb{N}-n]$$
(ii) $S_\infty$ is a topological group: the compatible metric is $d(x,y)=\frac{1}{2^{n+1}}$, where $n=\mathrm{inf}\{m\mid x(m)\ne y(m)\}$. Then $B(x,2^{-n})=\{y\mid x(i)=y(i) \forall i\le n,n\ge m-1\}$ and the result follows.
(iii) $S_\infty$ is not locally compact: I have no successful idea.
First, $\mathbf{N}^{\mathbf{N}}$ is a topological monoid. It has the complete metric $d(f,g)=\exp(-N(f,g))$ where $N(f,g)=\inf\{n:f(n)\neq g(n)\}$.
The group $S(\mathbf{N})$ (often denoted by $S_\infty$ but don't recommend this notation since it hides the set on which it acts) has the induced topology, which is a group topology. This topology was initially introduced by L. Onofri (1927), and was apparently rediscovered in the 50's.
A basis of closed neighborhoods of the identity $\mathrm{id}_\mathbf{N}$ is $(V_n)$, where $V_n$ is the (clopen) subgroup of permutations that are identity on $\mathbf{N}_{\le n}$.
Beware that $S(\mathbf{N})$ is not closed in $\mathbf{N}^{\mathbf{N}}$. However, the embedding $S(\mathbf{N})\to\mathbf{N}^{\mathbf{N}}\times\mathbf{N}^{\mathbf{N}}$, $g\mapsto (g,g^{-1})$ is a homeomorphism onto its closed image. This yields a complete metric on $S(\mathbf{N})$ defining the topology. Thus, $S(\mathbf{N})$ is a Polish space, hence is Baire.
$S(\mathbf{N})$ is not compact, since the set of $\sigma_n:k\mapsto k+n$ is an infinite closed discrete subset. Hence $V_n$ is not compact of any $n$, and hence $S(\mathbf{N})$ is not locally compact.
Added: here's a less direct argument, but rather of measure-theoretic flavor, of the failure of local compactness:
Since $(V_n)$ is a basis of open neighborhoods of 1, this clearly contradicts the existence of a left-invariant Haar measure.
The fact holds because $V_{n+1}$ has infinite index in $V_n$ and thus $V_n$ contains infinitely many pairwise disjoint left translates (=left cosets) of $V_{n+1}$. So, for every $n$, $\mu(V_n)<\infty$ implies $\mu(V_{n+1})=0$, which implies the fact.
An exercise: let $G$ be a closed subgroup of $S(\mathbf{N})$. Show that $G$ is locally compact if and only if there exists $n$ such that $G\cap V_n$ has only finite orbits on $\mathbf{N}$.
Edit: about $\mathsf{INJ}$ and $\mathsf{SURJ}$ being $G_\delta$:
$$\mathsf{INJ}=\bigcap_{n<m}A_{n,m}^c;\quad A_{n,m}=\{f\in\mathbf{N}^{\mathbf{N}}:f(n)=f(m)\};$$
$$\mathsf{SURJ}=\bigcap_nB_n^c;\quad B_n=(\mathbf{N}\smallsetminus\{n\})^{\mathbf{N}};$$
and each of $A_{n,m}$, $B_n$ is closed. (Note: $B_n$ has empty interior, and hence $\mathsf{SURJ}$ is $G_\delta$-dense in $\mathbf{N}^{\mathbf{N}}$. However $A_{n,m}$ is clopen, and clearly $\mathsf{INJ}$ is not dense in $\mathbf{N}^{\mathbf{N}}$; it's even closed.)