I have a question: "Is it true that $S^n \times [0,2\pi]/\sim \cong S^{n+1}$ where $S^{n}\times \{0\}$ collapses to a point and $S^n\times \{2\pi\}$ collapses to another point? "
Geometrically, this is true if $n=1$. The left hand side is a collection of circle, being the surface of a cylinder. After we collapse the top base and bottom base to points, we obtain a sphere.
Can we prove the general case with an explicit homeomorphism?
Yes, this is called a suspension https://en.wikipedia.org/wiki/Suspension_(topology)
in particular the suspension of $S^n$ is $S^{n+1}$.