Show that $$L_n''(0)=\frac{1}{2}n(n-1)$$
My first thought was to use the recurrence relation $$L_n^k(x)=L_{n-1}^k(x)+L_n^{k-1}(x)$$ and the orthogonality property $$\int_0^\infty e^{-x} x^kL_n^k(x)L_m^k(x)dx=\frac{(n+k)1}{n!},$$ for $k=2$, but doing so didn't seem to lead anywhere.
We know $L_n(0)=1$ and $L'_n(0)=-n$, so by derivation of Laguerre equation $$xy''+(1-x)y'+ny=0$$ again and set $x=0$ you will find it.