Are there any degree 7 polynomials over $\mathbb{Q}$ having Galois group $S_7$? If so, is there one for which this is easy to check with pencil and paper?
I know that for degree 3 polynomials, the Galois group will be $S_3$ if the discriminant is not a square in $\mathbb{Q}$, but I don't think the same holds for a degree 7.
Yes, there are even infinitely many examples with integer coefficients. This is a consequence of the Hilbert Irreducibility Theorem. See Serre's treatment of this at http://www.msc.uky.edu/sohum/ma561/notes/workspace/books/serre_galois_theory.pdf. There is also an article on the Hilbert Irreducibility Theorem in the latest number of the American Mathematical Monthly.