I have the following solution to the above problem:
Let $f(x)=2x-1-\sin(x)$
Observe, $2x-1, \sin(x)$ are continuous functions, hence by arithmetic of continuous functions $f(x)$ is continuous $\forall x$.
$f'(x)=2-\cos(x)$, hence $f'(x)>0$, $\forall x$ and hence $f(x)$ is increasing $\forall x$.
Observe $f(0)=-1<0$ and $f(\pi)=2\pi-1>0$ hence since $f(x)$ is continuous and increasing $\forall x$ there is exactly one real root.
I'm wondering if my solution would be considered acceptable and if there is an alternative way to go about solving this problem. Thanks!
As a slightly different proof, you can prove that $f$ has at least one root, and if you assume that has more than one roots, then by Rolle's s theorem, would exist $y\in \Bbb{R}$ such that $f'(y)=0$
Thus $\cos{y}=2$ which is a contradiction.