For note $|A| = n\ge 1$
$aSa$ so S is reflexive.
I'm unsure how you prove symmetry and transitivity when there's only one element. For symmetry, would you say that $aSa$ has the reverse $aSa$? But transitivity still wouldn't work.
There are $n $ equivalence class, $[a] = {a}$, as there is only one element per $a $ for the whole set A.
It doesn't matter whether there is only one element or not. Your assumption only refers to one element at a time. Go back to the definition. Symmetry means that $(xSy) \implies (ySx)$ If $x \neq y$ then both clauses are false and the implication is true. If $x=y$ both clauses are true and the implication is true. Thus the relation is symmetric. The proof of transitivity is similar.