Integrate
$$I=\int_{0}^{1}{x^{2n}-x\over 1+x}\cdot{dx\over \ln{x}}=\ln\left({2\over \pi}\cdot{(2n)!!\over (2n-1)!!}\right)\tag1$$
$${x^{2n}-x\over 1+x}=\sum_{k=0}^{\infty}(-1)^k(x^{2n}-x)x^k\tag2$$
Sub $(2)$ into $(1)\rightarrow (3)$
$$I=\sum_{n=0}^{\infty}\int_{0}^{1}(x^{2n+k}-x^{k+1})\cdot{dx\over \ln{x}}\tag3$$ Frullani's theorem
$$\int_{0}^{1}(x^m-x^n)\cdot{dx\over \ln{x}}=\ln{m+1 \over n+1}\tag4$$
Apply $(4)$ to $(3)\rightarrow (5)$
$$I=\sum_{n=0}^{\infty}(-1)^n\ln\left({2n+k+1\over k+2}\right)\tag5$$
$${2\over \pi}={(2n-1)!!\over (2n)!}\prod_{k=0}^{\infty}\left({2n+k+1\over k+2}\right)^{(-1)^k}\tag6$$
Enforce the substitution $x\to e^{-x}$ to write
$$\begin{align} I(n)&=\int_0^1 \frac{x^{2n}-x}{1+x}\frac{1}{\log(x)}\,dx\\\\ &=\int_0^\infty \frac{e^{-x}-e^{-2nx}}{x}\frac{e^{-x}}{1+e^{-x}}\,dx\\\\ &=\sum_{k=0}^\infty (-1)^k \int_0^\infty \frac{e^{-(k+2)x}-e^{-(k+2n+1)x}}{x}\\\\ &=\sum_{k=0}^\infty (-1)^k \log\left(\frac{k+2n+1}{k+2}\right)\\\\ &=\sum_{k=1}^\infty (-1)^{k-1} \log\left(\frac{k+2n}{k+1}\right)\\\\ \end{align}$$
Now, note that we can write the partial sum
$$\begin{align} \sum_{k=1}^{2N} (-1)^{k-1} \log\left(\frac{k+2n}{k+1}\right)&=\sum_{k=1}^N \log\left(\frac{2k-1+2n}{2k}\right)-\sum_{k=1}^N \log\left(\frac{2k+2n}{2k+1}\right)\\\\ &=\sum_{k=1}^N \log\left(\frac{2k-1+2n}{2k+2n}\right)+\sum_{k=1}^N \log\left(\frac{2k+1}{2k}\right)\\\\ &=\sum_{k=n+1}^{n+N} \log\left(\frac{2k-1}{2k}\right)+\sum_{k=1}^N \log\left(\frac{2k+1}{2k}\right)\\\\ &=\sum_{k=1}^{n+N} \log\left(\frac{2k-1}{2k}\right)+\sum_{k=1}^{n+N} \log\left(\frac{2k+1}{2k}\right)\\\\ &-\sum_{k=1}^{n} \log\left(\frac{2k-1}{2k}\right)-\sum_{k=N+1}^{n+N} \log\left(\frac{2k+1}{2k}\right)\\\\ &=\sum_{k=1}^{n+N} \log\left(\frac{(2k-1)(2k+1)}{(2k)(2k)}\right)\\\\ &+\log\left(\frac{(2n)!!}{(2n-1)!!}\right)-\sum_{k=N+1}^{n+N} \log\left(\frac{2k+1}{2k}\right)\\\\ \end{align}$$
Recalling Wallis' Product, we see that
$$\lim_{N\to \infty}\sum_{k=1}^{n+N} \log\left(\frac{(2k-1)(2k+1)}{(2k)(2k)}\right)=-\log(\pi/2)$$
And since $\lim_{N\to \infty}\sum_{k=N+1}^{n+N} \log\left(\frac{2k+1}{2k}\right)=0$, we find
$$I(n)=\log\left(\frac{2}{\pi}\frac{(2n)!!}{(2n-1)!!}\right)$$
as was to be shown!!
APPENDIX:
In THIS ANSWER, I evaluated the integral
$$J(n)=\int_0^1 \frac{x^{2n+1}-x}{1+x}\frac{1}{\log(x)}\,dx=\log\left(\frac{(2n+1)!!}{(2n)!!}\right)$$
by making use of the integral evaluated herein.