If we take the inner product $\langle f, g \rangle = \displaystyle\int_{-\pi}^{\pi} f(t) \overline{g(t)} dt$ on $L^2 ((-\pi, \pi))$, which allows functions to $\mathbb{C}$, then it's not hard to check that $\Big(\frac{e^{int}}{\sqrt{2\pi}}\Big)_{n=1}^{\infty}$ is an orthonormal sequence in the space, but I'm having trouble showing it to be an orthonormal basis -- i.e. a complete orthonormal sequence. I tried using the characterisation of complete orthonormal sequences telling us that for any $f \in L^2 ((-\pi, \pi))$, $$\displaystyle\sum_{n=1}^{\infty}|\langle f, e_n \rangle|^2 = ||f||^2,$$ where we define $e_n =\frac{e^{int}}{\sqrt{2\pi}},$ but the products on the left were difficult because they're not as easily transformable into ordinary complex line integrals as $\langle e_m, e_n \rangle$ is . Trying to use the definition -- where $\langle f, e_n \rangle = 0$ $\forall n \in \mathbb{N}$ $\implies f=0$ -- but that presents the same difficulty.
Is there a simple way of proving the completeness of this sequence?
It isn't a basis - you need to let $n$ range over $\mathbb Z$. Specifcally, if $e_n(t)=\frac{e^{int}}{\sqrt{2\pi}}$, then $\{e_n\}_{n\in\mathbb Z}$ is a basis of $L^2(-\pi,\pi)$. The easiest way to prove this is to use Stone-Weierstrass.
Let $X:=\{f:[-\pi,\pi]\to\mathbb R: f\text{ is continuous, }f(-\pi)=f(\pi)\}$. Observe that we can identify $X$ with the set of continuous functions on the torus $\mathbb T$, which is a compact metric space. Now if we define $\mathcal A=\operatorname{span}\{e_n:n\in\mathbb Z\}$, $\mathcal A$ is a sub-algebra of $X$; it is clearly a subspace and it is closed under multiplication since $e_ne_m=\frac1{\sqrt{2\pi}}e_{n+m}$. We apply the Stone-Weierstrass theorem to deduce that $\mathcal A$ is dense in $X$ (in the uniform topology). There are three conditions we need to check:
Hence the Stone-Weierstrass theorem applies: for every $f\in X$, there exists a sequence $\{f_k\}$ in $\mathcal A$ suchb that $f_k\to f$ uniformly. This implies $f_k\to f$ in $L^2$, and hence $\mathcal A$ is $L^2$-dense in $X$. Since $X$ is $L^2$-dense in $L^2(-\pi,\pi)$, the proof is complete.