A pre-additive category with a single object $\bullet$ is simply a ring $R = \mathrm{Hom}(\bullet,\bullet)$: pre-additivity makes this Hom-space an abelian group and with bilinear composition, i.e. a distributive product.
Out of idle curiosity I am wondering what happens to the ring if we ask for the category to be additive.
Since an additive category has a zero object it follows that an additive category with one object is the trivial ring (i.e. the ring with only one element).