Suppose $a=\alpha+2\beta$ and $b=3\alpha+5\beta$. Then by solving this, we get $\alpha=2b-5a$ and $\beta=3a-b$.
I tried substitution method to solve this, but i couldn't get the above solutions viz., $\alpha$ and $\beta$.
I am afraid if this is too basic and it might not be appropriate for this site.
Multiply $a=\alpha+2\beta$ by $3$ to get $3a=3\alpha+6\beta.$
Now subtract this from $b=3\alpha+5\beta$ to get $\beta=3a-b$.
Similarly, if you multiply $a=\alpha+2\beta$ by $5$ and $b=3\alpha+5\beta$ by $2$,
you can subtract the equations to eliminate $\beta $ and solve for $\alpha$.
Or you could say $a=\alpha+2(3a-b)$ and solve for $\alpha$ that way.