I've tried to solve the equation $\cot \theta = 2\cot 2\theta$ with the command 'Reduce' of Mathematica and obtained $\theta = n\pi$ as the solution with n an integer. But $\theta=n\pi$ is clearly a singularity in a cotangent function so this is puzzling.
I've realized that the above equation can be simplified to: $\tan \theta=0$, and that is probably what Mathematica does to obtain the solution, but again, how $\theta=n\pi$ can be the solution if it is not in the domain of a $\cot$ function? Is that an inconsistency in Mathematica or am I missing something?
HINT: your equation is equivalent to $$\frac{1}{\cot(\theta)}=0$$