Consider that you are looking for the zero(s) of function
$$f(x)=5^{2x-1}-6e^{x-1}+1$$ for which
$$f'(x)=2\ 5^{2 x-1} \log (5)-6 e^{x-1}$$
$$f''(x)=4\ 5^{2 x-1} \log ^2(5)-6 e^{x-1}$$ If you notice that the first derivative can write before simplifications as $$f'(x)=6e^{x-1}\left(\exp\left[(2x-1)\log(5)+\log(2)+\log(\log(5))-(x-1)-\log(6) \right]-1 \right)$$ it cancels at $x_*$ (which makes the argument of the exponential term equal to $0$) given by
$$x_*=\frac{\log \left(\frac{15}{ \log (5)}\right)-1}{2 \log (5)-1}\approx 0.555311$$ At this point
$$f(x_*)\approx-1.65127 \qquad \text{and} \qquad f''(x_*)\approx 8.53411$$ So, two roots and one of them is obvious.
For the second one, you need a numerical method such as Newton; but it requires a reasonable starting point. By inspection or graphing, you will notice that the second solution is between $0$ and $-1$ since $f(0)=\frac{6}{5}-\frac{6}{e}\approx -1.00728 $ and $f(-1)=\frac{126}{125}-\frac{6}{e^2}\approx 0.195988$.
So start the iterations using $x_0=-1$ and get the following iterates
$$\left(
\begin{array}{cc}
n & x_n \\
0 & -1.0000000000 \\
1 & -0.7507336913 \\
2 & -0.7751463191 \\
3 & -0.7754101823 \\
4 & -0.7754102129
\end{array}
\right)$$ which is the solution for ten significant figures.
Consider that you are looking for the zero(s) of function $$f(x)=5^{2x-1}-6e^{x-1}+1$$ for which $$f'(x)=2\ 5^{2 x-1} \log (5)-6 e^{x-1}$$ $$f''(x)=4\ 5^{2 x-1} \log ^2(5)-6 e^{x-1}$$ If you notice that the first derivative can write before simplifications as $$f'(x)=6e^{x-1}\left(\exp\left[(2x-1)\log(5)+\log(2)+\log(\log(5))-(x-1)-\log(6) \right]-1 \right)$$ it cancels at $x_*$ (which makes the argument of the exponential term equal to $0$) given by $$x_*=\frac{\log \left(\frac{15}{ \log (5)}\right)-1}{2 \log (5)-1}\approx 0.555311$$ At this point $$f(x_*)\approx-1.65127 \qquad \text{and} \qquad f''(x_*)\approx 8.53411$$ So, two roots and one of them is obvious.
For the second one, you need a numerical method such as Newton; but it requires a reasonable starting point. By inspection or graphing, you will notice that the second solution is between $0$ and $-1$ since $f(0)=\frac{6}{5}-\frac{6}{e}\approx -1.00728 $ and $f(-1)=\frac{126}{125}-\frac{6}{e^2}\approx 0.195988$.
So start the iterations using $x_0=-1$ and get the following iterates $$\left( \begin{array}{cc} n & x_n \\ 0 & -1.0000000000 \\ 1 & -0.7507336913 \\ 2 & -0.7751463191 \\ 3 & -0.7754101823 \\ 4 & -0.7754102129 \end{array} \right)$$ which is the solution for ten significant figures.