My friend asked me this question and he also sent me his solution and just wanted to check if its correct or not. Can you guys check it. What he did was,
$6^{2x}-9^x=6^2-9$
then he equated the terms with the same bases, i.e
$6^{2x}=6^2 and -9^x=-9$
in this way $x = 1$.
I have a feeling that this isn't correct but also cant think of counter example as well. Thank you for your help :)
It is equivalent to $$9^x4^x-9^x=27$$ which is $$9^x(4^x-1)=27$$ where $f : x \to 9^x(4^x-1)$ is stricly increasing on $\mathbb{R}^+$ hence the solution is unique and
$$ S=\{1\}$$