I want to solve the differential equation $f'(x)=f(x)$ using power series of the form $$f(x)=\sum_{n=0}^{\infty}{c_nx^n}$$
From my previous knowledge I know that the solution is $f(x)=c_0e^x$ I can justify that using MacLaurin series, but how do I show the process? Also, why does $c_n=c_{n-1}$?
It is not true that $c_n = c_{n-1}$, you must have made a mistake in your differentiation.
The actual recurrence relation you should obtain for the coefficients is $c_n = c_{n-1} / n$. This equation is easy to solve, and it indeed does give the coefficients for $e^x$ as you expect it to.