Stokes' Theorem from PMA Rudin. Confusing moment with simplex

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I am reading the proof of Stokes' theorem from PMA Rudin but one moment seems to very weird. enter image description here

Why Rudin considers the case when $\sigma=[0,\mathbf{e}_1,\dots, \mathbf{e}_k]$? After all $\sigma$ may take the form $[\mathbf{p}_0, \mathbf{p}_1,\dots, \mathbf{p}_k]$.

Can anyone explain this important moment?

I can't understand it by myself.